TY - JOUR
T1 - Photocatalytic reactions of acetic acid on platinum-loaded TiO2
T2 - ESR evidence of radical intermediates in the photo-Kolbe reaction
AU - Kaise, M.
AU - Kondoh, H.
AU - Nishihara, C.
AU - Nozoye, H.
AU - Shindo, H.
AU - Nimura, S.
AU - Kikuchi, O.
PY - 1993/12/1
Y1 - 1993/12/1
N2 - Two elusive radical intermediates; a methyl radical (·CH 3) and a carboxymethyl radical (·CH2CO 2H), have been confirmed for the first time by direct observation of their ESR absorptions at room temperature on the photocatalytic reactions of acetic acid and metal (platinum)-loaded titanium dioxide (Pt/TiO2) in aqueous solution.
AB - Two elusive radical intermediates; a methyl radical (·CH 3) and a carboxymethyl radical (·CH2CO 2H), have been confirmed for the first time by direct observation of their ESR absorptions at room temperature on the photocatalytic reactions of acetic acid and metal (platinum)-loaded titanium dioxide (Pt/TiO2) in aqueous solution.
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U2 - 10.1039/C39930000395
DO - 10.1039/C39930000395
M3 - Article
AN - SCOPUS:37049082018
SN - 0022-4936
SP - 395
EP - 396
JO - Journal of the Chemical Society, Chemical Communications
JF - Journal of the Chemical Society, Chemical Communications
IS - 4
ER -