Photodissociation of Mg(CH2=CHCN)n+: Excited electronic states of n = 1 and 2 and intracluster electron transfer for n = 3 and 4

Ari Furuya; Keijiro Ohshimo; Hironori Tsunoyama; Fuminori Misaizu; Koichi Ohno; Hidekazu Watanabe

doi:10.1063/1.1541020

Photodissociation of Mg(CH₂=CHCN)_n⁺: Excited electronic states of n = 1 and 2 and intracluster electron transfer for n = 3 and 4

Ari Furuya
, Keijiro Ohshimo
, Hironori Tsunoyama
, Fuminori Misaizu
, Koichi Ohno
, Hidekazu Watanabe

Research output: Contribution to journal › Article › peer-review

8 Citations (Scopus)

Abstract

Clusters of Mg⁺ with AN molecules, Mg(AN)_n⁺, were investigated by photodissociation spectroscopy and theoretical calculations. In the dissociation spectrum of n=1, two absorption bands were observed at 26 400 and 40 800 cm^-1. On the other hand, three absorption bands centered at 22 600, 28 800, and 37 500 cm^-1 appeared for n=2. These absorption bands were assigned by using DFT(B3LYP/6-31+G*) and CIS/6-31+G* methods.

Original language	English
Pages (from-to)	5456-5464
Number of pages	9
Journal	Journal of Chemical Physics
Volume	118
Issue number	12
DOIs	https://doi.org/10.1063/1.1541020
Publication status	Published - 2003 Mar 22
Externally published	Yes

ASJC Scopus subject areas

General Physics and Astronomy
Physical and Theoretical Chemistry

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10.1063/1.1541020

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title = "Photodissociation of Mg(CH2=CHCN)n+: Excited electronic states of n = 1 and 2 and intracluster electron transfer for n = 3 and 4",

abstract = "Clusters of Mg+ with AN molecules, Mg(AN)n+, were investigated by photodissociation spectroscopy and theoretical calculations. In the dissociation spectrum of n=1, two absorption bands were observed at 26 400 and 40 800 cm-1. On the other hand, three absorption bands centered at 22 600, 28 800, and 37 500 cm-1 appeared for n=2. These absorption bands were assigned by using DFT(B3LYP/6-31+G*) and CIS/6-31+G* methods.",

author = "Ari Furuya and Keijiro Ohshimo and Hironori Tsunoyama and Fuminori Misaizu and Koichi Ohno and Hidekazu Watanabe",

year = "2003",

month = mar,

day = "22",

doi = "10.1063/1.1541020",

language = "English",

volume = "118",

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publisher = "American Institute of Physics",

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T1 - Photodissociation of Mg(CH2=CHCN)n+

T2 - Excited electronic states of n = 1 and 2 and intracluster electron transfer for n = 3 and 4

AU - Furuya, Ari

AU - Ohshimo, Keijiro

AU - Tsunoyama, Hironori

AU - Misaizu, Fuminori

AU - Ohno, Koichi

AU - Watanabe, Hidekazu

PY - 2003/3/22

Y1 - 2003/3/22

N2 - Clusters of Mg+ with AN molecules, Mg(AN)n+, were investigated by photodissociation spectroscopy and theoretical calculations. In the dissociation spectrum of n=1, two absorption bands were observed at 26 400 and 40 800 cm-1. On the other hand, three absorption bands centered at 22 600, 28 800, and 37 500 cm-1 appeared for n=2. These absorption bands were assigned by using DFT(B3LYP/6-31+G*) and CIS/6-31+G* methods.

AB - Clusters of Mg+ with AN molecules, Mg(AN)n+, were investigated by photodissociation spectroscopy and theoretical calculations. In the dissociation spectrum of n=1, two absorption bands were observed at 26 400 and 40 800 cm-1. On the other hand, three absorption bands centered at 22 600, 28 800, and 37 500 cm-1 appeared for n=2. These absorption bands were assigned by using DFT(B3LYP/6-31+G*) and CIS/6-31+G* methods.

UR - https://www.scopus.com/pages/publications/0037461017

UR - https://www.scopus.com/pages/publications/0037461017#tab=citedBy

U2 - 10.1063/1.1541020

DO - 10.1063/1.1541020

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SN - 0021-9606

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JO - Journal of Chemical Physics

JF - Journal of Chemical Physics

IS - 12

ER -

Photodissociation of Mg(CH₂=CHCN)_n⁺: Excited electronic states of n = 1 and 2 and intracluster electron transfer for n = 3 and 4

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