Photoelectron spectroscopy of (C6F6)-                         n and (Au-C6F6)- clusters

A. Nakajima; T. Taguwa; K. Hoshino; T. Sugioka; T. Naganuma; F. Oho; K. Watanabe; K. Nakao; Y. Konishi; R. Kishi; K. Kaya

doi:10.1016/0009-2614(93)85449-X

Photoelectron spectroscopy of (C₆F₆)^- _n and (Au-C₆F₆)^- clusters

A. Nakajima, T. Taguwa, K. Hoshino, T. Sugioka, T. Naganuma, F. Oho, K. Watanabe, K. Nakao, Y. Konishi, R. Kishi, K. Kaya

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108 Citations (Scopus)

Abstract

Photoelectron spectra of hexafluorobenzene (C₆F₆) cluster anions and its Au complex anion were measured in the gas phase at the photon energy of 3.49 eV, using a magnetic bottle electron spectrometer having ≈ 80 meV resolution. The spectra show unresolved broad features: The vertical detachment energies (VDEs) were determined from the maxima of the spectra. The VDE of (C₆F₆)^- _n gradually increases by 0.1-0.2 eV with the cluster size (n=1-8) from 1.56(3) to 2.54(6) eV, and the VDE of (Au-C₆F₆)^- anion is 1.99(5) eV.

Original language	English
Pages (from-to)	22-26
Number of pages	5
Journal	Chemical Physics Letters
Volume	214
Issue number	1
DOIs	https://doi.org/10.1016/0009-2614(93)85449-X
Publication status	Published - 1993 Oct 22
Externally published	Yes

ASJC Scopus subject areas

Physics and Astronomy(all)
Physical and Theoretical Chemistry

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10.1016/0009-2614(93)85449-X

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title = "Photoelectron spectroscopy of (C6F6)- n and (Au-C6F6)- clusters",

abstract = "Photoelectron spectra of hexafluorobenzene (C6F6) cluster anions and its Au complex anion were measured in the gas phase at the photon energy of 3.49 eV, using a magnetic bottle electron spectrometer having ≈ 80 meV resolution. The spectra show unresolved broad features: The vertical detachment energies (VDEs) were determined from the maxima of the spectra. The VDE of (C6F6)- n gradually increases by 0.1-0.2 eV with the cluster size (n=1-8) from 1.56(3) to 2.54(6) eV, and the VDE of (Au-C6F6)- anion is 1.99(5) eV.",

author = "A. Nakajima and T. Taguwa and K. Hoshino and T. Sugioka and T. Naganuma and F. Oho and K. Watanabe and K. Nakao and Y. Konishi and R. Kishi and K. Kaya",

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doi = "10.1016/0009-2614(93)85449-X",

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TY - JOUR

T1 - Photoelectron spectroscopy of (C6F6)- n and (Au-C6F6)- clusters

AU - Nakajima, A.

AU - Taguwa, T.

AU - Hoshino, K.

AU - Sugioka, T.

AU - Naganuma, T.

AU - Oho, F.

AU - Watanabe, K.

AU - Nakao, K.

AU - Konishi, Y.

AU - Kishi, R.

AU - Kaya, K.

PY - 1993/10/22

Y1 - 1993/10/22

N2 - Photoelectron spectra of hexafluorobenzene (C6F6) cluster anions and its Au complex anion were measured in the gas phase at the photon energy of 3.49 eV, using a magnetic bottle electron spectrometer having ≈ 80 meV resolution. The spectra show unresolved broad features: The vertical detachment energies (VDEs) were determined from the maxima of the spectra. The VDE of (C6F6)- n gradually increases by 0.1-0.2 eV with the cluster size (n=1-8) from 1.56(3) to 2.54(6) eV, and the VDE of (Au-C6F6)- anion is 1.99(5) eV.

AB - Photoelectron spectra of hexafluorobenzene (C6F6) cluster anions and its Au complex anion were measured in the gas phase at the photon energy of 3.49 eV, using a magnetic bottle electron spectrometer having ≈ 80 meV resolution. The spectra show unresolved broad features: The vertical detachment energies (VDEs) were determined from the maxima of the spectra. The VDE of (C6F6)- n gradually increases by 0.1-0.2 eV with the cluster size (n=1-8) from 1.56(3) to 2.54(6) eV, and the VDE of (Au-C6F6)- anion is 1.99(5) eV.

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DO - 10.1016/0009-2614(93)85449-X

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VL - 214

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EP - 26

JO - Chemical Physics Letters

JF - Chemical Physics Letters

IS - 1

ER -

Photoelectron spectroscopy of (C₆F₆)^- _n and (Au-C₆F₆)^- clusters

Abstract

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