Polymeric and monomeric forms of a schiff base-nitridomanganese(V) complex. Synthesis and crystal structure

Masanobu Tsuchimoto; Hirofumi Iwamoto; Masaaki Kojima; Shigeru Ohba

doi:10.1246/cl.2000.1156

Polymeric and monomeric forms of a schiff base-nitridomanganese(V) complex. Synthesis and crystal structure

Masanobu Tsuchimoto
, Hirofumi Iwamoto
, Masaaki Kojima
, Shigeru Ohba

Department of Humanities and Social Sciences

Research output: Contribution to journal › Article › peer-review

10 Citations (Scopus)

Abstract

A novel polymeric nitridomanganese(V) complex with a Schiff base ligand [MnN(salpn)] (H₂(salpn): N,N′-disalicylidene-1,3-propanediamine) (1) was prepared by photolysis of the azidomanganese(III) complex, [MnN₃salpn)] in acetonitrile. The monomeric complex (2) was obtained by recrystallization of 1 from methanol. X-ray crystal structure analyses of 1 and 2 were carried out. The brown complex 1 has a linear ⋯Mn≡N⋯Mn≡N⋯ chain structure.

Original language	English
Pages (from-to)	1156-1157
Number of pages	2
Journal	Chemistry Letters
Issue number	10
DOIs	https://doi.org/10.1246/cl.2000.1156
Publication status	Published - 2000

ASJC Scopus subject areas

General Chemistry

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10.1246/cl.2000.1156

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abstract = "A novel polymeric nitridomanganese(V) complex with a Schiff base ligand [MnN(salpn)] (H2(salpn): N,N′-disalicylidene-1,3-propanediamine) (1) was prepared by photolysis of the azidomanganese(III) complex, [MnN3salpn)] in acetonitrile. The monomeric complex (2) was obtained by recrystallization of 1 from methanol. X-ray crystal structure analyses of 1 and 2 were carried out. The brown complex 1 has a linear ⋯Mn≡N⋯Mn≡N⋯ chain structure.",

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doi = "10.1246/cl.2000.1156",

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journal = "Chemistry Letters",

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AU - Tsuchimoto, Masanobu

AU - Iwamoto, Hirofumi

AU - Kojima, Masaaki

AU - Ohba, Shigeru

PY - 2000

Y1 - 2000

N2 - A novel polymeric nitridomanganese(V) complex with a Schiff base ligand [MnN(salpn)] (H2(salpn): N,N′-disalicylidene-1,3-propanediamine) (1) was prepared by photolysis of the azidomanganese(III) complex, [MnN3salpn)] in acetonitrile. The monomeric complex (2) was obtained by recrystallization of 1 from methanol. X-ray crystal structure analyses of 1 and 2 were carried out. The brown complex 1 has a linear ⋯Mn≡N⋯Mn≡N⋯ chain structure.

AB - A novel polymeric nitridomanganese(V) complex with a Schiff base ligand [MnN(salpn)] (H2(salpn): N,N′-disalicylidene-1,3-propanediamine) (1) was prepared by photolysis of the azidomanganese(III) complex, [MnN3salpn)] in acetonitrile. The monomeric complex (2) was obtained by recrystallization of 1 from methanol. X-ray crystal structure analyses of 1 and 2 were carried out. The brown complex 1 has a linear ⋯Mn≡N⋯Mn≡N⋯ chain structure.

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JO - Chemistry Letters

JF - Chemistry Letters

IS - 10

ER -

Polymeric and monomeric forms of a schiff base-nitridomanganese(V) complex. Synthesis and crystal structure

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