Preparation and characterization of mono-imidazole ligated (meso-tetramesitylporphyrinato)iron(III) complexes: Model for cytochromes c'

Akira Ikezaki; Mikio Nakamura

doi:10.1246/cl.2000.994

Preparation and characterization of mono-imidazole ligated (meso-tetramesitylporphyrinato)iron(III) complexes: Model for cytochromes c'

Akira Ikezaki, Mikio Nakamura

Research output: Contribution to journal › Article › peer-review

7 Citations (Scopus)

Abstract

A series of mono-imidazole ligated (meso-tetramesitylporphyrinato)iron(III) complexes have been prepared. The spin states of these complexes are presented as the admixed intermediate (S = 3/2, 5/2) on the basis of the ¹H NMR, ¹³C NMR, EPR, and magnetic moments. The S = 3/2 character has increased as the axial imidazole ligand becomes bulkier.

Original language	English
Pages (from-to)	994-995
Number of pages	2
Journal	Chemistry Letters
Issue number	9
DOIs	https://doi.org/10.1246/cl.2000.994
Publication status	Published - 2000
Externally published	Yes

ASJC Scopus subject areas

General Chemistry

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10.1246/cl.2000.994

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abstract = "A series of mono-imidazole ligated (meso-tetramesitylporphyrinato)iron(III) complexes have been prepared. The spin states of these complexes are presented as the admixed intermediate (S = 3/2, 5/2) on the basis of the 1H NMR, 13C NMR, EPR, and magnetic moments. The S = 3/2 character has increased as the axial imidazole ligand becomes bulkier.",

author = "Akira Ikezaki and Mikio Nakamura",

year = "2000",

doi = "10.1246/cl.2000.994",

language = "English",

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journal = "Chemistry Letters",

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T1 - Preparation and characterization of mono-imidazole ligated (meso-tetramesitylporphyrinato)iron(III) complexes

T2 - Model for cytochromes c'

AU - Ikezaki, Akira

AU - Nakamura, Mikio

PY - 2000

Y1 - 2000

N2 - A series of mono-imidazole ligated (meso-tetramesitylporphyrinato)iron(III) complexes have been prepared. The spin states of these complexes are presented as the admixed intermediate (S = 3/2, 5/2) on the basis of the 1H NMR, 13C NMR, EPR, and magnetic moments. The S = 3/2 character has increased as the axial imidazole ligand becomes bulkier.

AB - A series of mono-imidazole ligated (meso-tetramesitylporphyrinato)iron(III) complexes have been prepared. The spin states of these complexes are presented as the admixed intermediate (S = 3/2, 5/2) on the basis of the 1H NMR, 13C NMR, EPR, and magnetic moments. The S = 3/2 character has increased as the axial imidazole ligand becomes bulkier.

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IS - 9

ER -

Preparation and characterization of mono-imidazole ligated (meso-tetramesitylporphyrinato)iron(III) complexes: Model for cytochromes c'

Abstract

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