Processing-structure-mechanical property relationships of semicrystalline polyolefin-based block copolymers

Fanny Deplace; Zhigang Wang; Nathaniel Lynd; Atsushi Hotta; Jeffrey Rose; Philip Hustad; Jun Tian; Hisashi Ohtaki; Geoffrey Coates; Fumihiko Shimizu; Kousou Hirokane; Fumiyoshi Yamada; Yong Woo Shin; Lixia Rong; Jie Zhu; Shigeyuki Toki; Benjamin Hsiao; Glenn Fredrickson; Edward Kramer

doi:10.1002/polb.21969

Processing-structure-mechanical property relationships of semicrystalline polyolefin-based block copolymers

Fanny Deplace, Zhigang Wang, Nathaniel Lynd, Atsushi Hotta, Jeffrey Rose, Philip Hustad, Jun Tian, Hisashi Ohtaki, Geoffrey Coates, Fumihiko Shimizu, Kousou Hirokane, Fumiyoshi Yamada, Yong Woo Shin, Lixia Rong, Jie Zhu, Shigeyuki Toki, Benjamin Hsiao, Glenn Fredrickson, Edward Kramer

Research output: Contribution to journal › Article › peer-review

39 Citations (Scopus)

Abstract

The incremental plastic deformation of the crystals of block copolymers made of semicrystalline polypropylene endblocks and amorphous ethylene-r-propylene midblocks occurring during step cycle tensile tests has dramatic effects on the stress-strain curves. This can be understood from the evolution of the morphology and of the microstructure of the crystalline blocks revealed by X-ray scattering experiments.

Original language	English
Pages (from-to)	1428-1437
Number of pages	10
Journal	Journal of Polymer Science, Part B: Polymer Physics
Volume	48
Issue number	13
DOIs	https://doi.org/10.1002/polb.21969
Publication status	Published - 2010 Jul 1
Externally published	Yes

Keywords

Block copolymers
Elastomers
Mechanical properties
Polyolefins
Saxs
Thermoplastics
Waxs

ASJC Scopus subject areas

Condensed Matter Physics
Physical and Theoretical Chemistry
Polymers and Plastics
Materials Chemistry

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Deplace, F., Wang, Z., Lynd, N., Hotta, A., Rose, J., Hustad, P., Tian, J., Ohtaki, H., Coates, G., Shimizu, F., Hirokane, K., Yamada, F., Shin, Y. W., Rong, L., Zhu, J., Toki, S., Hsiao, B., Fredrickson, G., & Kramer, E. (2010). Processing-structure-mechanical property relationships of semicrystalline polyolefin-based block copolymers. Journal of Polymer Science, Part B: Polymer Physics, 48(13), 1428-1437. https://doi.org/10.1002/polb.21969

Deplace, F, Wang, Z, Lynd, N, Hotta, A, Rose, J, Hustad, P, Tian, J, Ohtaki, H, Coates, G, Shimizu, F, Hirokane, K, Yamada, F, Shin, YW, Rong, L, Zhu, J, Toki, S, Hsiao, B, Fredrickson, G & Kramer, E 2010, 'Processing-structure-mechanical property relationships of semicrystalline polyolefin-based block copolymers', Journal of Polymer Science, Part B: Polymer Physics, vol. 48, no. 13, pp. 1428-1437. https://doi.org/10.1002/polb.21969

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abstract = "The incremental plastic deformation of the crystals of block copolymers made of semicrystalline polypropylene endblocks and amorphous ethylene-r-propylene midblocks occurring during step cycle tensile tests has dramatic effects on the stress-strain curves. This can be understood from the evolution of the morphology and of the microstructure of the crystalline blocks revealed by X-ray scattering experiments.",

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AU - Deplace, Fanny

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AU - Rose, Jeffrey

AU - Hustad, Philip

AU - Tian, Jun

AU - Ohtaki, Hisashi

AU - Coates, Geoffrey

AU - Shimizu, Fumihiko

AU - Hirokane, Kousou

AU - Yamada, Fumiyoshi

AU - Shin, Yong Woo

AU - Rong, Lixia

AU - Zhu, Jie

AU - Toki, Shigeyuki

AU - Hsiao, Benjamin

AU - Fredrickson, Glenn

AU - Kramer, Edward

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KW - Mechanical properties

KW - Polyolefins

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KW - Thermoplastics

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Processing-structure-mechanical property relationships of semicrystalline polyolefin-based block copolymers

Abstract

Keywords

ASJC Scopus subject areas

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