Ruthenium-catalyzed addition of aromatic esters at the ortho C-H bonds to olefins

Motohiro Sonoda; Fumitoshi Kakiuchi; Asayuki Kamatani; Naoto Chatani; Shinji Murai

doi:10.1246/cl.1996.109

Ruthenium-catalyzed addition of aromatic esters at the ortho C-H bonds to olefins

Motohiro Sonoda, Fumitoshi Kakiuchi, Asayuki Kamatani, Naoto Chatani, Shinji Murai

Research output: Contribution to journal › Article › peer-review

107 Citations (Scopus)

Abstract

A ruthenium complex, Ru(H)₂(CO)(PPh₃)₃, can catalyze the addition of aromatic and heteroaromatic esters at the ortho carbonhydrogen bonds to olefinic double bonds. While un-substituted alkyl benzoate did not react, those substituted with CF₃ or F underwent smooth catalytic addition. A heteroaromatic ester and a benzo-δ-lactone also reacted.

Original language	English
Pages (from-to)	109-110
Number of pages	2
Journal	Chemistry Letters
Issue number	2
DOIs	https://doi.org/10.1246/cl.1996.109
Publication status	Published - 1996 Jan 1
Externally published	Yes

ASJC Scopus subject areas

Chemistry(all)

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10.1246/cl.1996.109

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abstract = "A ruthenium complex, Ru(H)2(CO)(PPh3)3, can catalyze the addition of aromatic and heteroaromatic esters at the ortho carbonhydrogen bonds to olefinic double bonds. While un-substituted alkyl benzoate did not react, those substituted with CF3 or F underwent smooth catalytic addition. A heteroaromatic ester and a benzo-δ-lactone also reacted.",

author = "Motohiro Sonoda and Fumitoshi Kakiuchi and Asayuki Kamatani and Naoto Chatani and Shinji Murai",

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AU - Sonoda, Motohiro

AU - Kakiuchi, Fumitoshi

AU - Kamatani, Asayuki

AU - Chatani, Naoto

AU - Murai, Shinji

PY - 1996/1/1

Y1 - 1996/1/1

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AB - A ruthenium complex, Ru(H)2(CO)(PPh3)3, can catalyze the addition of aromatic and heteroaromatic esters at the ortho carbonhydrogen bonds to olefinic double bonds. While un-substituted alkyl benzoate did not react, those substituted with CF3 or F underwent smooth catalytic addition. A heteroaromatic ester and a benzo-δ-lactone also reacted.

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Ruthenium-catalyzed addition of aromatic esters at the ortho C-H bonds to olefins

Abstract

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