Selective 1,4-reduction of α,β-unsaturated carbonyl compounds by combined use of bis(1,3-diketonato)cobalt(II) complex and diisobutylaluminum hydride

Taketo Ikeno; Tomomi Kimura; Yuhki Ohtsuka; Tohru Yamada

doi:10.1055/s-1999-2557

Selective 1,4-reduction of α,β-unsaturated carbonyl compounds by combined use of bis(1,3-diketonato)cobalt(II) complex and diisobutylaluminum hydride

Taketo Ikeno, Tomomi Kimura, Yuhki Ohtsuka, Tohru Yamada

Department of Chemistry

Research output: Contribution to journal › Article › peer-review

20 Citations (Scopus)

Abstract

By the combined use of CO(acac)₂ with DIBAL, various α,β-unsaturated carbonyl compounds such as enones, α,β-unsaturated carboxylates and carboxamides were selectively reduced in a 1,4-manner to obtain the corresponding 1,4-reduced products in good-to-high yields.

Original language	English
Pages (from-to)	96-98
Number of pages	3
Journal	Synlett
Issue number	1
DOIs	https://doi.org/10.1055/s-1999-2557
Publication status	Published - 1999 Jan 1

Keywords

1,4-reduction
Bis(acetylacetonato)cobalt(II) complex
Cobalt hydride
Diisobutylaluminum hydride
α,β-unsaturated carbonyl compound

ASJC Scopus subject areas

Organic Chemistry

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10.1055/s-1999-2557

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title = "Selective 1,4-reduction of α,β-unsaturated carbonyl compounds by combined use of bis(1,3-diketonato)cobalt(II) complex and diisobutylaluminum hydride",

abstract = "By the combined use of CO(acac)2 with DIBAL, various α,β-unsaturated carbonyl compounds such as enones, α,β-unsaturated carboxylates and carboxamides were selectively reduced in a 1,4-manner to obtain the corresponding 1,4-reduced products in good-to-high yields.",

keywords = "1,4-reduction, Bis(acetylacetonato)cobalt(II) complex, Cobalt hydride, Diisobutylaluminum hydride, α,β-unsaturated carbonyl compound",

author = "Taketo Ikeno and Tomomi Kimura and Yuhki Ohtsuka and Tohru Yamada",

year = "1999",

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doi = "10.1055/s-1999-2557",

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T1 - Selective 1,4-reduction of α,β-unsaturated carbonyl compounds by combined use of bis(1,3-diketonato)cobalt(II) complex and diisobutylaluminum hydride

AU - Ikeno, Taketo

AU - Kimura, Tomomi

AU - Ohtsuka, Yuhki

AU - Yamada, Tohru

PY - 1999/1/1

Y1 - 1999/1/1

N2 - By the combined use of CO(acac)2 with DIBAL, various α,β-unsaturated carbonyl compounds such as enones, α,β-unsaturated carboxylates and carboxamides were selectively reduced in a 1,4-manner to obtain the corresponding 1,4-reduced products in good-to-high yields.

AB - By the combined use of CO(acac)2 with DIBAL, various α,β-unsaturated carbonyl compounds such as enones, α,β-unsaturated carboxylates and carboxamides were selectively reduced in a 1,4-manner to obtain the corresponding 1,4-reduced products in good-to-high yields.

KW - 1,4-reduction

KW - Bis(acetylacetonato)cobalt(II) complex

KW - Cobalt hydride

KW - Diisobutylaluminum hydride

KW - α,β-unsaturated carbonyl compound

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ER -

Selective 1,4-reduction of α,β-unsaturated carbonyl compounds by combined use of bis(1,3-diketonato)cobalt(II) complex and diisobutylaluminum hydride

Abstract

Keywords

ASJC Scopus subject areas

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