Selective dioxygenation of cyclohexane catalysed by hydrogen peroxide and dinuclear iron(III) complexes with μ-alkoxo bridges

Satoshi Nishino; Hiroyuki Hosomi; Shigeru Ohba; Hideaki Matsushima; Tadashi Tokii; Yuzo Nishida

doi:10.1039/a809725i

Selective dioxygenation of cyclohexane catalysed by hydrogen peroxide and dinuclear iron(III) complexes with μ-alkoxo bridges

Satoshi Nishino, Hiroyuki Hosomi, Shigeru Ohba, Hideaki Matsushima, Tadashi Tokii, Yuzo Nishida

Department of Humanities and Social Sciences

Research output: Contribution to journal › Article › peer-review

30 Citations (Scopus)

Abstract

Several dinuclear iron(III) complexes with μ-alkoxo bridges gave predominantly cyclohexyl hydroperoxide in the reaction with cyclohexane and hydrogen peroxide, and similar results were observed when linear n-alkanes, such as n-nonane and n-octane, were used instead of cyclohexane. A mechanism for selective formation of the hydroperoxide is discussed.

Original language	English
Pages (from-to)	1509-1513
Number of pages	5
Journal	Journal of the Chemical Society - Dalton Transactions
Issue number	9
DOIs	https://doi.org/10.1039/a809725i
Publication status	Published - 1999 May 7

ASJC Scopus subject areas

Chemistry(all)

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title = "Selective dioxygenation of cyclohexane catalysed by hydrogen peroxide and dinuclear iron(III) complexes with μ-alkoxo bridges",

abstract = "Several dinuclear iron(III) complexes with μ-alkoxo bridges gave predominantly cyclohexyl hydroperoxide in the reaction with cyclohexane and hydrogen peroxide, and similar results were observed when linear n-alkanes, such as n-nonane and n-octane, were used instead of cyclohexane. A mechanism for selective formation of the hydroperoxide is discussed.",

author = "Satoshi Nishino and Hiroyuki Hosomi and Shigeru Ohba and Hideaki Matsushima and Tadashi Tokii and Yuzo Nishida",

year = "1999",

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T1 - Selective dioxygenation of cyclohexane catalysed by hydrogen peroxide and dinuclear iron(III) complexes with μ-alkoxo bridges

AU - Nishino, Satoshi

AU - Hosomi, Hiroyuki

AU - Ohba, Shigeru

AU - Matsushima, Hideaki

AU - Tokii, Tadashi

AU - Nishida, Yuzo

PY - 1999/5/7

Y1 - 1999/5/7

N2 - Several dinuclear iron(III) complexes with μ-alkoxo bridges gave predominantly cyclohexyl hydroperoxide in the reaction with cyclohexane and hydrogen peroxide, and similar results were observed when linear n-alkanes, such as n-nonane and n-octane, were used instead of cyclohexane. A mechanism for selective formation of the hydroperoxide is discussed.

AB - Several dinuclear iron(III) complexes with μ-alkoxo bridges gave predominantly cyclohexyl hydroperoxide in the reaction with cyclohexane and hydrogen peroxide, and similar results were observed when linear n-alkanes, such as n-nonane and n-octane, were used instead of cyclohexane. A mechanism for selective formation of the hydroperoxide is discussed.

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Selective dioxygenation of cyclohexane catalysed by hydrogen peroxide and dinuclear iron(III) complexes with μ-alkoxo bridges

Abstract

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