Selective nitrous oxide oxidation for C-H oxidation and aromatization of 9,10-dihydroanthracene derivatives

Kentaro Hashimoto; Hirotaka Tanaka; Taketo Ikeno; Tohru Yamada

doi:10.1246/cl.2002.582

Selective nitrous oxide oxidation for C-H oxidation and aromatization of 9,10-dihydroanthracene derivatives

Kentaro Hashimoto, Hirotaka Tanaka, Taketo Ikeno, Tohru Yamada

Department of Chemistry

Research output: Contribution to journal › Article › peer-review

30 Citations (Scopus)

Abstract

During the nitrous oxide oxidation of 9,10-dihydroanthracene derivatives catalyzed by the ruthenium-porphyrin complexes, anthraquinones were selectively afforded by the C-H oxidation of the benzylic carbon under the appropriate reaction conditions, whereas anthracenes as a result of oxidative aromatization were selectively obtained in the presence of sulfuric acid.

Original language	English
Pages (from-to)	582-583
Number of pages	2
Journal	Chemistry Letters
Issue number	6
DOIs	https://doi.org/10.1246/cl.2002.582
Publication status	Published - 2002 Apr 5

ASJC Scopus subject areas

Chemistry(all)

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10.1246/cl.2002.582

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title = "Selective nitrous oxide oxidation for C-H oxidation and aromatization of 9,10-dihydroanthracene derivatives",

abstract = "During the nitrous oxide oxidation of 9,10-dihydroanthracene derivatives catalyzed by the ruthenium-porphyrin complexes, anthraquinones were selectively afforded by the C-H oxidation of the benzylic carbon under the appropriate reaction conditions, whereas anthracenes as a result of oxidative aromatization were selectively obtained in the presence of sulfuric acid.",

author = "Kentaro Hashimoto and Hirotaka Tanaka and Taketo Ikeno and Tohru Yamada",

year = "2002",

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T1 - Selective nitrous oxide oxidation for C-H oxidation and aromatization of 9,10-dihydroanthracene derivatives

AU - Hashimoto, Kentaro

AU - Tanaka, Hirotaka

AU - Ikeno, Taketo

AU - Yamada, Tohru

PY - 2002/4/5

Y1 - 2002/4/5

N2 - During the nitrous oxide oxidation of 9,10-dihydroanthracene derivatives catalyzed by the ruthenium-porphyrin complexes, anthraquinones were selectively afforded by the C-H oxidation of the benzylic carbon under the appropriate reaction conditions, whereas anthracenes as a result of oxidative aromatization were selectively obtained in the presence of sulfuric acid.

AB - During the nitrous oxide oxidation of 9,10-dihydroanthracene derivatives catalyzed by the ruthenium-porphyrin complexes, anthraquinones were selectively afforded by the C-H oxidation of the benzylic carbon under the appropriate reaction conditions, whereas anthracenes as a result of oxidative aromatization were selectively obtained in the presence of sulfuric acid.

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DO - 10.1246/cl.2002.582

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Selective nitrous oxide oxidation for C-H oxidation and aromatization of 9,10-dihydroanthracene derivatives

Abstract

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