Selective nitrous oxide oxidation for C-H oxidation and aromatization of 9,10-dihydroanthracene derivatives

Kentaro Hashimoto; Hirotaka Tanaka; Taketo Ikeno; Tohru Yamada

doi:10.1246/cl.2002.582

Selective nitrous oxide oxidation for C-H oxidation and aromatization of 9,10-dihydroanthracene derivatives

Kentaro Hashimoto
, Hirotaka Tanaka
, Taketo Ikeno
, Tohru Yamada

Department of Chemistry

Research output: Contribution to journal › Article › peer-review

33 Citations (Scopus)

Abstract

During the nitrous oxide oxidation of 9,10-dihydroanthracene derivatives catalyzed by the ruthenium-porphyrin complexes, anthraquinones were selectively afforded by the C-H oxidation of the benzylic carbon under the appropriate reaction conditions, whereas anthracenes as a result of oxidative aromatization were selectively obtained in the presence of sulfuric acid.

Original language	English
Pages (from-to)	582-583
Number of pages	2
Journal	Chemistry Letters
Issue number	6
DOIs	https://doi.org/10.1246/cl.2002.582
Publication status	Published - 2002 Apr 5

ASJC Scopus subject areas

General Chemistry

Access to Document

10.1246/cl.2002.582

Cite this

@article{925f15097efb4459bf634237c615a99a,

title = "Selective nitrous oxide oxidation for C-H oxidation and aromatization of 9,10-dihydroanthracene derivatives",

abstract = "During the nitrous oxide oxidation of 9,10-dihydroanthracene derivatives catalyzed by the ruthenium-porphyrin complexes, anthraquinones were selectively afforded by the C-H oxidation of the benzylic carbon under the appropriate reaction conditions, whereas anthracenes as a result of oxidative aromatization were selectively obtained in the presence of sulfuric acid.",

author = "Kentaro Hashimoto and Hirotaka Tanaka and Taketo Ikeno and Tohru Yamada",

year = "2002",

month = apr,

day = "5",

doi = "10.1246/cl.2002.582",

language = "English",

pages = "582--583",

journal = "Chemistry Letters",

issn = "0366-7022",

publisher = "Oxford University Press",

number = "6",

}

TY - JOUR

T1 - Selective nitrous oxide oxidation for C-H oxidation and aromatization of 9,10-dihydroanthracene derivatives

AU - Hashimoto, Kentaro

AU - Tanaka, Hirotaka

AU - Ikeno, Taketo

AU - Yamada, Tohru

PY - 2002/4/5

Y1 - 2002/4/5

N2 - During the nitrous oxide oxidation of 9,10-dihydroanthracene derivatives catalyzed by the ruthenium-porphyrin complexes, anthraquinones were selectively afforded by the C-H oxidation of the benzylic carbon under the appropriate reaction conditions, whereas anthracenes as a result of oxidative aromatization were selectively obtained in the presence of sulfuric acid.

AB - During the nitrous oxide oxidation of 9,10-dihydroanthracene derivatives catalyzed by the ruthenium-porphyrin complexes, anthraquinones were selectively afforded by the C-H oxidation of the benzylic carbon under the appropriate reaction conditions, whereas anthracenes as a result of oxidative aromatization were selectively obtained in the presence of sulfuric acid.

UR - https://www.scopus.com/pages/publications/0036335825

UR - https://www.scopus.com/pages/publications/0036335825#tab=citedBy

U2 - 10.1246/cl.2002.582

DO - 10.1246/cl.2002.582

M3 - Article

AN - SCOPUS:0036335825

SN - 0366-7022

SP - 582

EP - 583

JO - Chemistry Letters

JF - Chemistry Letters

IS - 6

ER -

Selective nitrous oxide oxidation for C-H oxidation and aromatization of 9,10-dihydroanthracene derivatives

Abstract

ASJC Scopus subject areas

Access to Document

Other files and links

Fingerprint

Cite this