Self-oscillating polymer brushes

Tsukuru Masuda; Mio Hidaka; Yoko Murase; Aya Mizutani Akimoto; Kenichi Nagase; Teruo Okano; Ryo Yoshida

doi:10.1002/anie.201301988

Self-oscillating polymer brushes

Tsukuru Masuda, Mio Hidaka, Yoko Murase, Aya Mizutani Akimoto, Kenichi Nagase, Teruo Okano, Ryo Yoshida

Research output: Contribution to journal › Article › peer-review

65 Citations (Scopus)

Abstract

An autonomous functional surface has been designed by using self-oscillating polymers that convert the chemical energy of the Belousov-Zhabotinsky reaction into conformational changes of the polymer chains (see picture: red: hydrophobic/collapsed, green: hydrophilic/extended). Self-oscillating polymer brushes were grafted onto the inner surface of a glass capillary, and autonomous propagation of a chemical wave was observed.

Original language	English
Pages (from-to)	7468-7471
Number of pages	4
Journal	Angewandte Chemie - International Edition
Volume	52
Issue number	29
DOIs	https://doi.org/10.1002/anie.201301988
Publication status	Published - 2013 Jul 15
Externally published	Yes

Keywords

ATRP
functional surfaces
oscillating reactions
polymer brushes
ruthenium

ASJC Scopus subject areas

Catalysis
General Chemistry

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10.1002/anie.201301988

Cite this

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keywords = "ATRP, functional surfaces, oscillating reactions, polymer brushes, ruthenium",

author = "Tsukuru Masuda and Mio Hidaka and Yoko Murase and Akimoto, {Aya Mizutani} and Kenichi Nagase and Teruo Okano and Ryo Yoshida",

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T1 - Self-oscillating polymer brushes

AU - Masuda, Tsukuru

AU - Hidaka, Mio

AU - Murase, Yoko

AU - Akimoto, Aya Mizutani

AU - Nagase, Kenichi

AU - Okano, Teruo

AU - Yoshida, Ryo

PY - 2013/7/15

Y1 - 2013/7/15

N2 - An autonomous functional surface has been designed by using self-oscillating polymers that convert the chemical energy of the Belousov-Zhabotinsky reaction into conformational changes of the polymer chains (see picture: red: hydrophobic/collapsed, green: hydrophilic/extended). Self-oscillating polymer brushes were grafted onto the inner surface of a glass capillary, and autonomous propagation of a chemical wave was observed.

AB - An autonomous functional surface has been designed by using self-oscillating polymers that convert the chemical energy of the Belousov-Zhabotinsky reaction into conformational changes of the polymer chains (see picture: red: hydrophobic/collapsed, green: hydrophilic/extended). Self-oscillating polymer brushes were grafted onto the inner surface of a glass capillary, and autonomous propagation of a chemical wave was observed.

KW - ATRP

KW - functional surfaces

KW - oscillating reactions

KW - polymer brushes

KW - ruthenium

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JO - Angewandte Chemie - International Edition

JF - Angewandte Chemie - International Edition

IS - 29

ER -

Self-oscillating polymer brushes

Abstract

Keywords

ASJC Scopus subject areas

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