Silyl group transfer from allylsilanes to olefins catalyzed by a ruthenium(II) complex

Fumitoshi Kakiuchi; Airi Yamada; Naoto Chatani; Shinji Murai; Naoyuki Furukawa; Yoshio Seki

doi:10.1021/om9810450

Silyl group transfer from allylsilanes to olefins catalyzed by a ruthenium(II) complex

Fumitoshi Kakiuchi, Airi Yamada, Naoto Chatani, Shinji Murai, Naoyuki Furukawa, Yoshio Seki

Research output: Contribution to journal › Article › peer-review

30 Citations (Scopus)

Abstract

Dehydrogenative silylation of olefins, such as styrenes, methyl acrylate, and vinyl ether, using allyltriethoxysilane as the source of the silyl group can be catalyzed by RuHCl(CO)(PPh ₃ ) ₃ to give the corresponding vinylsilanes in good to excellent yields. The ruthenium complex also catalyzed the self-dehydrogenative silylation of allylsilanes, yielding 1,3-bis(triorganosilyl)-propenes.

Original language	English
Pages (from-to)	2033-2036
Number of pages	4
Journal	Organometallics
Volume	18
Issue number	10
DOIs	https://doi.org/10.1021/om9810450
Publication status	Published - 1999 May 10
Externally published	Yes

ASJC Scopus subject areas

Physical and Theoretical Chemistry
Organic Chemistry
Inorganic Chemistry

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10.1021/om9810450

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abstract = " Dehydrogenative silylation of olefins, such as styrenes, methyl acrylate, and vinyl ether, using allyltriethoxysilane as the source of the silyl group can be catalyzed by RuHCl(CO)(PPh 3 ) 3 to give the corresponding vinylsilanes in good to excellent yields. The ruthenium complex also catalyzed the self-dehydrogenative silylation of allylsilanes, yielding 1,3-bis(triorganosilyl)-propenes.",

author = "Fumitoshi Kakiuchi and Airi Yamada and Naoto Chatani and Shinji Murai and Naoyuki Furukawa and Yoshio Seki",

year = "1999",

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T1 - Silyl group transfer from allylsilanes to olefins catalyzed by a ruthenium(II) complex

AU - Kakiuchi, Fumitoshi

AU - Yamada, Airi

AU - Chatani, Naoto

AU - Murai, Shinji

AU - Furukawa, Naoyuki

AU - Seki, Yoshio

PY - 1999/5/10

Y1 - 1999/5/10

N2 - Dehydrogenative silylation of olefins, such as styrenes, methyl acrylate, and vinyl ether, using allyltriethoxysilane as the source of the silyl group can be catalyzed by RuHCl(CO)(PPh 3 ) 3 to give the corresponding vinylsilanes in good to excellent yields. The ruthenium complex also catalyzed the self-dehydrogenative silylation of allylsilanes, yielding 1,3-bis(triorganosilyl)-propenes.

AB - Dehydrogenative silylation of olefins, such as styrenes, methyl acrylate, and vinyl ether, using allyltriethoxysilane as the source of the silyl group can be catalyzed by RuHCl(CO)(PPh 3 ) 3 to give the corresponding vinylsilanes in good to excellent yields. The ruthenium complex also catalyzed the self-dehydrogenative silylation of allylsilanes, yielding 1,3-bis(triorganosilyl)-propenes.

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Silyl group transfer from allylsilanes to olefins catalyzed by a ruthenium(II) complex

Abstract

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