TY - JOUR
T1 - (SP-4-1 )-Bis{aqua(1R,2R)-N,N′-bis(salicylidene)-cyclohexane-1, 2-diy[diamine-κ 4O,N,N′,O′]man-ganese(III)}-di-μ-cyano-κ 4N:C-[dicyanonickel(II)]
AU - Akitsu, Takashiro
AU - Takeuchi, Yuiri
AU - Einaga, Yasuaki
PY - 2005/3/1
Y1 - 2005/3/1
N2 - The title compound. [Mn2Ni(C20H20N 2O2)2(CN)4(H2O) 2], is the first chiral trinuclear complex having an Mn III-NC-NiII-CN-MnIII unit. A pair of the trans sites of [Ni(CN)4]2- links two MnIII units. The MnIII ion has a pseudo-octahedral coordination geometry with the four donor atoms of the tetradentate chiral Schiff base forming the equatorial plane, and with a bridging cyanide and an aqua ligand at the axial positions.
AB - The title compound. [Mn2Ni(C20H20N 2O2)2(CN)4(H2O) 2], is the first chiral trinuclear complex having an Mn III-NC-NiII-CN-MnIII unit. A pair of the trans sites of [Ni(CN)4]2- links two MnIII units. The MnIII ion has a pseudo-octahedral coordination geometry with the four donor atoms of the tetradentate chiral Schiff base forming the equatorial plane, and with a bridging cyanide and an aqua ligand at the axial positions.
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U2 - 10.1107/S160053680500379X
DO - 10.1107/S160053680500379X
M3 - Article
AN - SCOPUS:18544382253
SN - 1600-5368
VL - 61
SP - m502-m505
JO - Acta Crystallographica Section E: Structure Reports Online
JF - Acta Crystallographica Section E: Structure Reports Online
IS - 3
ER -