Stereocontrolled synthesis of a highly functionalized 1,7-dioxaspiro[4.4]Nonane derivative related to antibiotic pseurotins

Shin ya Aoki; Takahiro Ohi; Kazuya Shimizu; Ryota Shiraki; Ken ichi Takao; Kin ichi Tadano

Stereocontrolled synthesis of a highly functionalized 1,7-dioxaspiro[4.4]Nonane derivative related to antibiotic pseurotins

Shin ya Aoki, Takahiro Ohi, Kazuya Shimizu, Ryota Shiraki, Ken ichi Takao, Kin ichi Tadano

Department of Applied Chemistry

Research output: Contribution to journal › Article › peer-review

12 Citations (Scopus)

Abstract

For a total synthesis of pseurotins, unusual heterospirocyclic antibiotics, a key intermediate (5), having a highly functionalized 1,7-dioxaspiro-[4.4]nonane structure, has been synthesized from diacetone D-glucose.

Original language	English
Pages (from-to)	57-61
Number of pages	5
Journal	Heterocycles
Volume	58
Publication status	Published - 2002 Nov 22

ASJC Scopus subject areas

Analytical Chemistry
Pharmacology
Organic Chemistry

Cite this

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title = "Stereocontrolled synthesis of a highly functionalized 1,7-dioxaspiro[4.4]Nonane derivative related to antibiotic pseurotins",

abstract = "For a total synthesis of pseurotins, unusual heterospirocyclic antibiotics, a key intermediate (5), having a highly functionalized 1,7-dioxaspiro-[4.4]nonane structure, has been synthesized from diacetone D-glucose.",

author = "Aoki, {Shin ya} and Takahiro Ohi and Kazuya Shimizu and Ryota Shiraki and Takao, {Ken ichi} and Tadano, {Kin ichi}",

year = "2002",

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publisher = "Japan Institute of Heterocyclic Chemistry",

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T1 - Stereocontrolled synthesis of a highly functionalized 1,7-dioxaspiro[4.4]Nonane derivative related to antibiotic pseurotins

AU - Aoki, Shin ya

AU - Ohi, Takahiro

AU - Shimizu, Kazuya

AU - Shiraki, Ryota

AU - Takao, Ken ichi

AU - Tadano, Kin ichi

PY - 2002/11/22

Y1 - 2002/11/22

N2 - For a total synthesis of pseurotins, unusual heterospirocyclic antibiotics, a key intermediate (5), having a highly functionalized 1,7-dioxaspiro-[4.4]nonane structure, has been synthesized from diacetone D-glucose.

AB - For a total synthesis of pseurotins, unusual heterospirocyclic antibiotics, a key intermediate (5), having a highly functionalized 1,7-dioxaspiro-[4.4]nonane structure, has been synthesized from diacetone D-glucose.

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M3 - Article

AN - SCOPUS:0037159720

SN - 0385-5414

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JO - Heterocycles

JF - Heterocycles

ER -

Stereocontrolled synthesis of a highly functionalized 1,7-dioxaspiro[4.4]Nonane derivative related to antibiotic pseurotins

Abstract

ASJC Scopus subject areas

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