Stereoselective preparation of α-hydroxycarboxamide by manganese complex catalyzed hydration of α,β-unsaturated carboxamide with molecular oxygen and phenylsilane

Mitsuo Sato; Yasuhiko Gunji; Taketo Ikeno; Tohru Yamada

doi:10.1246/cl.2004.1304

Stereoselective preparation of α-hydroxycarboxamide by manganese complex catalyzed hydration of α,β-unsaturated carboxamide with molecular oxygen and phenylsilane

Mitsuo Sato, Yasuhiko Gunji, Taketo Ikeno, Tohru Yamada

Department of Chemistry

Research output: Contribution to journal › Article › peer-review

15 Citations (Scopus)

Abstract

Aerobic oxidation with the combined use of phenylsilane and a manganese complex catalyst was successfully applied to the α,β-unsaturated carboxamide containing a C₂-symmetrical chiral auxiliary to afford the corresponding α-hydroxycarboxamide in good-to-high yield with high stereoselectivity.

Original language	English
Article number	CL-040824
Pages (from-to)	1304-1305
Number of pages	2
Journal	Chemistry Letters
Volume	33
Issue number	10
DOIs	https://doi.org/10.1246/cl.2004.1304
Publication status	Published - 2004 Oct 5

ASJC Scopus subject areas

Chemistry(all)

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10.1246/cl.2004.1304

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title = "Stereoselective preparation of α-hydroxycarboxamide by manganese complex catalyzed hydration of α,β-unsaturated carboxamide with molecular oxygen and phenylsilane",

abstract = "Aerobic oxidation with the combined use of phenylsilane and a manganese complex catalyst was successfully applied to the α,β-unsaturated carboxamide containing a C2-symmetrical chiral auxiliary to afford the corresponding α-hydroxycarboxamide in good-to-high yield with high stereoselectivity.",

author = "Mitsuo Sato and Yasuhiko Gunji and Taketo Ikeno and Tohru Yamada",

year = "2004",

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journal = "Chemistry Letters",

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T1 - Stereoselective preparation of α-hydroxycarboxamide by manganese complex catalyzed hydration of α,β-unsaturated carboxamide with molecular oxygen and phenylsilane

AU - Sato, Mitsuo

AU - Gunji, Yasuhiko

AU - Ikeno, Taketo

AU - Yamada, Tohru

PY - 2004/10/5

Y1 - 2004/10/5

N2 - Aerobic oxidation with the combined use of phenylsilane and a manganese complex catalyst was successfully applied to the α,β-unsaturated carboxamide containing a C2-symmetrical chiral auxiliary to afford the corresponding α-hydroxycarboxamide in good-to-high yield with high stereoselectivity.

AB - Aerobic oxidation with the combined use of phenylsilane and a manganese complex catalyst was successfully applied to the α,β-unsaturated carboxamide containing a C2-symmetrical chiral auxiliary to afford the corresponding α-hydroxycarboxamide in good-to-high yield with high stereoselectivity.

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DO - 10.1246/cl.2004.1304

M3 - Article

AN - SCOPUS:11844282141

SN - 0366-7022

VL - 33

SP - 1304

EP - 1305

JO - Chemistry Letters

JF - Chemistry Letters

IS - 10

M1 - CL-040824

ER -

Stereoselective preparation of α-hydroxycarboxamide by manganese complex catalyzed hydration of α,β-unsaturated carboxamide with molecular oxygen and phenylsilane

Abstract

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