Strong, Resilient, and Sustainable Aliphatic Polyester Thermoplastic Elastomers

Annabelle Watts, Naruki Kurokawa, Marc A. Hillmyer

Research output: Contribution to journalArticlepeer-review

129 Citations (Scopus)


Thermoplastic elastomers (TPEs) composed of ABA block polymers exhibit a wide variety of properties and are easily processable as they contain physical, rather than chemical, cross-links. Poly(γ-methyl-Îμ -caprolactone) (PγMCL) is an amorphous polymer with a low entanglement molar mass (Me = 2.9 kg mol-1), making it a suitable choice for tough elastomers. Incorporating PγMCL as the midblock with polylactide (PLA) end blocks (fLA = 0.17) results in TPEs with high stresses and elongations at break (σB = 24 ± 2 MPa and ϵB = 1029 ± 20%, respectively) and low levels of hysteresis. The use of isotactic PLA as the end blocks (fLLA = 0.17) increases the strength and toughness of the material (σB = 30 ± 4 MPa, ϵB = 988 ± 30%) due to its semicrystalline nature. This study aims to demonstrate how the outstanding properties in these sustainable materials are a result of the entanglements, glass transition temperature, segment-segment interaction parameter, and crystallinity, resulting in comparable properties to the commercially relevant styrene-based TPEs.

Original languageEnglish
Pages (from-to)1845-1854
Number of pages10
Issue number6
Publication statusPublished - 2017 Jun 12
Externally publishedYes

ASJC Scopus subject areas

  • Bioengineering
  • Biomaterials
  • Polymers and Plastics
  • Materials Chemistry


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