Sulphate ester of trans-4-hydroxypipecolic acid in seeds of Peltophorum

Stephen V. Evans; Tony K.M. Shing; Robin T. Aplin; Linda E. Fellows; George W.J. Fleet

doi:10.1016/S0031-9422(00)80675-5

Sulphate ester of trans-4-hydroxypipecolic acid in seeds of Peltophorum

Stephen V. Evans, Tony K.M. Shing, Robin T. Aplin, Linda E. Fellows, George W.J. Fleet

Department of Chemistry

Research output: Contribution to journal › Article › peer-review

27 Citations (Scopus)

Abstract

An acidic compound isolated from seed of the legume Peltophorum africanum has been characterised on the basis of FAB-MS, EIMS, ¹³C and ¹H NMR as trans-4-hydroxypipecolic acid-4-sulphate. This is the first naturally occurring sulphate ester of a non-protein amino acid to be described. The possible systematic significance of the distribution of the ester within Peltophorum and related genera is considered.

Original language	English
Pages (from-to)	2593-2596
Number of pages	4
Journal	Phytochemistry
Volume	24
Issue number	11
DOIs	https://doi.org/10.1016/S0031-9422(00)80675-5
Publication status	Published - 1985 Oct 29

Keywords

C NMR
EIMS
FAB-MS
H NMR
Leguminosae
Peltophorum africanum
chemotaxonomy.
non-protein amino acid
sulphate ester
trans-4-hydroxypipecolic acid-4-sulphate

ASJC Scopus subject areas

Biochemistry
Molecular Biology
Plant Science
Horticulture

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10.1016/S0031-9422(00)80675-5

Cite this

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title = "Sulphate ester of trans-4-hydroxypipecolic acid in seeds of Peltophorum",

abstract = "An acidic compound isolated from seed of the legume Peltophorum africanum has been characterised on the basis of FAB-MS, EIMS, 13C and 1H NMR as trans-4-hydroxypipecolic acid-4-sulphate. This is the first naturally occurring sulphate ester of a non-protein amino acid to be described. The possible systematic significance of the distribution of the ester within Peltophorum and related genera is considered.",

keywords = "C NMR, EIMS, FAB-MS, H NMR, Leguminosae, Peltophorum africanum, chemotaxonomy., non-protein amino acid, sulphate ester, trans-4-hydroxypipecolic acid-4-sulphate",

author = "Evans, {Stephen V.} and Shing, {Tony K.M.} and Aplin, {Robin T.} and Fellows, {Linda E.} and Fleet, {George W.J.}",

year = "1985",

month = oct,

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doi = "10.1016/S0031-9422(00)80675-5",

language = "English",

volume = "24",

pages = "2593--2596",

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T1 - Sulphate ester of trans-4-hydroxypipecolic acid in seeds of Peltophorum

AU - Evans, Stephen V.

AU - Shing, Tony K.M.

AU - Aplin, Robin T.

AU - Fellows, Linda E.

AU - Fleet, George W.J.

PY - 1985/10/29

Y1 - 1985/10/29

N2 - An acidic compound isolated from seed of the legume Peltophorum africanum has been characterised on the basis of FAB-MS, EIMS, 13C and 1H NMR as trans-4-hydroxypipecolic acid-4-sulphate. This is the first naturally occurring sulphate ester of a non-protein amino acid to be described. The possible systematic significance of the distribution of the ester within Peltophorum and related genera is considered.

AB - An acidic compound isolated from seed of the legume Peltophorum africanum has been characterised on the basis of FAB-MS, EIMS, 13C and 1H NMR as trans-4-hydroxypipecolic acid-4-sulphate. This is the first naturally occurring sulphate ester of a non-protein amino acid to be described. The possible systematic significance of the distribution of the ester within Peltophorum and related genera is considered.

KW - C NMR

KW - EIMS

KW - FAB-MS

KW - H NMR

KW - Leguminosae

KW - Peltophorum africanum

KW - chemotaxonomy.

KW - non-protein amino acid

KW - sulphate ester

KW - trans-4-hydroxypipecolic acid-4-sulphate

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DO - 10.1016/S0031-9422(00)80675-5

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SN - 0031-9422

VL - 24

SP - 2593

EP - 2596

JO - Phytochemistry

JF - Phytochemistry

IS - 11

ER -

Sulphate ester of trans-4-hydroxypipecolic acid in seeds of Peltophorum

Abstract

Keywords

ASJC Scopus subject areas

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