Sumanenylferrocenes and their solid state self-assembly

Berit Topolinski; Bernd M. Schmidt; Shuhei Higashibayashi; Hidehiro Sakurai; Dieter Lentz

doi:10.1039/c3dt51569a

Sumanenylferrocenes and their solid state self-assembly

Berit Topolinski, Bernd M. Schmidt, Shuhei Higashibayashi, Hidehiro Sakurai, Dieter Lentz

Research output: Contribution to journal › Article › peer-review

15 Citations (Scopus)

Abstract

The first ferrocene-fused organometallic compounds derived from the buckybowl sumanene (C₂₁H₁₂) are presented. Both compounds, sumanenylferrocene and 1,1′-disumanenylferrocene, have been synthesized by Negishi-type cross-coupling of iodosumanene and were studied crystallographically. Sumanenylferrocenes form unique packing motifs, which are both different from those of their corannulene congeners and sumanene itself.

Original language	English
Pages (from-to)	13809-13812
Number of pages	4
Journal	Dalton Transactions
Volume	42
Issue number	38
DOIs	https://doi.org/10.1039/c3dt51569a
Publication status	Published - 2013 Oct 14
Externally published	Yes

ASJC Scopus subject areas

Inorganic Chemistry

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10.1039/c3dt51569a

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abstract = "The first ferrocene-fused organometallic compounds derived from the buckybowl sumanene (C21H12) are presented. Both compounds, sumanenylferrocene and 1,1′-disumanenylferrocene, have been synthesized by Negishi-type cross-coupling of iodosumanene and were studied crystallographically. Sumanenylferrocenes form unique packing motifs, which are both different from those of their corannulene congeners and sumanene itself.",

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AU - Topolinski, Berit

AU - Schmidt, Bernd M.

AU - Higashibayashi, Shuhei

AU - Sakurai, Hidehiro

AU - Lentz, Dieter

PY - 2013/10/14

Y1 - 2013/10/14

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AB - The first ferrocene-fused organometallic compounds derived from the buckybowl sumanene (C21H12) are presented. Both compounds, sumanenylferrocene and 1,1′-disumanenylferrocene, have been synthesized by Negishi-type cross-coupling of iodosumanene and were studied crystallographically. Sumanenylferrocenes form unique packing motifs, which are both different from those of their corannulene congeners and sumanene itself.

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JO - Dalton Transactions

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Sumanenylferrocenes and their solid state self-assembly

Abstract

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