Synthesis and character of new bis(isoxazoline) ligands

Toshio Shinohara; Kazuhiko Wakita; Midori A. Arai; Takayoshi Arai; Hiroaki Sasai

doi:10.3987/com-02-s57

Synthesis and character of new bis(isoxazoline) ligands

Toshio Shinohara, Kazuhiko Wakita, Midori A. Arai, Takayoshi Arai, Hiroaki Sasai

Research output: Contribution to journal › Article › peer-review

11 Citations (Scopus)

Abstract

Synthesis of two kinds of new bis(isoxazoline) ligand, achiral 2,2'bis(isoxazolinyl)propane and (R)-2,2'-bis(isoxazolinyl)-1,1'-binaphthyl bearing an axial chirality is described. Both of the bis(isoxazoline) ligands accelerated the Pd(II)-catalyzed Wacker-type cyclization of alkenyl alcohol. The isoxazoline ligands were found to be essential to promote the cyclization.

Original language	English
Pages (from-to)	587-593
Number of pages	7
Journal	Heterocycles
Volume	59
Issue number	2
DOIs	https://doi.org/10.3987/com-02-s57
Publication status	Published - 2003 Mar 1
Externally published	Yes

ASJC Scopus subject areas

Analytical Chemistry
Pharmacology
Organic Chemistry

Access to Document

10.3987/com-02-s57

Cite this

@article{1dd7dcee0db7464ca8fa5756621e6eac,

title = "Synthesis and character of new bis(isoxazoline) ligands",

abstract = "Synthesis of two kinds of new bis(isoxazoline) ligand, achiral 2,2'bis(isoxazolinyl)propane and (R)-2,2'-bis(isoxazolinyl)-1,1'-binaphthyl bearing an axial chirality is described. Both of the bis(isoxazoline) ligands accelerated the Pd(II)-catalyzed Wacker-type cyclization of alkenyl alcohol. The isoxazoline ligands were found to be essential to promote the cyclization.",

author = "Toshio Shinohara and Kazuhiko Wakita and Arai, {Midori A.} and Takayoshi Arai and Hiroaki Sasai",

year = "2003",

month = mar,

day = "1",

doi = "10.3987/com-02-s57",

language = "English",

volume = "59",

pages = "587--593",

journal = "Heterocycles",

issn = "0385-5414",

publisher = "Japan Institute of Heterocyclic Chemistry",

number = "2",

}

TY - JOUR

T1 - Synthesis and character of new bis(isoxazoline) ligands

AU - Shinohara, Toshio

AU - Wakita, Kazuhiko

AU - Arai, Midori A.

AU - Arai, Takayoshi

AU - Sasai, Hiroaki

PY - 2003/3/1

Y1 - 2003/3/1

N2 - Synthesis of two kinds of new bis(isoxazoline) ligand, achiral 2,2'bis(isoxazolinyl)propane and (R)-2,2'-bis(isoxazolinyl)-1,1'-binaphthyl bearing an axial chirality is described. Both of the bis(isoxazoline) ligands accelerated the Pd(II)-catalyzed Wacker-type cyclization of alkenyl alcohol. The isoxazoline ligands were found to be essential to promote the cyclization.

AB - Synthesis of two kinds of new bis(isoxazoline) ligand, achiral 2,2'bis(isoxazolinyl)propane and (R)-2,2'-bis(isoxazolinyl)-1,1'-binaphthyl bearing an axial chirality is described. Both of the bis(isoxazoline) ligands accelerated the Pd(II)-catalyzed Wacker-type cyclization of alkenyl alcohol. The isoxazoline ligands were found to be essential to promote the cyclization.

UR - http://www.scopus.com/inward/record.url?scp=0037344469&partnerID=8YFLogxK

UR - http://www.scopus.com/inward/citedby.url?scp=0037344469&partnerID=8YFLogxK

U2 - 10.3987/com-02-s57

DO - 10.3987/com-02-s57

M3 - Article

AN - SCOPUS:0037344469

SN - 0385-5414

VL - 59

SP - 587

EP - 593

JO - Heterocycles

JF - Heterocycles

IS - 2

ER -

Synthesis and character of new bis(isoxazoline) ligands

Abstract

ASJC Scopus subject areas

Access to Document

Other files and links

Fingerprint

Cite this