Synthesis and crystal structures of polymeric nitridomanganese(V) and nitridochromium(V) complexes with a tetradentate schiff base ligand

Masanobu Tsuchimoto; Hirofumi Iwamoto; Masaaki Kojima; Shigeru Ohba

doi:10.1080/10587250210760

Synthesis and crystal structures of polymeric nitridomanganese(V) and nitridochromium(V) complexes with a tetradentate schiff base ligand

Masanobu Tsuchimoto
, Hirofumi Iwamoto
, Masaaki Kojima
, Shigeru Ohba

Department of Humanities and Social Sciences

Research output: Contribution to journal › Conference article › peer-review

1 Citation (Scopus)

Abstract

Novel polymeric nitridomanganese(V) and nitridochromium(V) complexes with a Schiff base ligand, [MnN(salpn)] and [CrN(salpn)] (H₂(salpn): N,N'-disalicylidene-1,3-propanediamine) were prepared by photolysis of azido complexes. X-ray crystal structure analyses show that the complexes have an isostructual polymeric structure (⋯M≡N⋯M≡N⋯) with the N⋯M distances being 2.528(3) Å for M=Mn, and 2.508(2) Å for M=Cr.

Original language	English
Pages (from-to)	33-38
Number of pages	6
Journal	Molecular Crystals and Liquid Crystals Science and Technology, Section A: Molecular Crystals and Liquid Crystals
Volume	376
DOIs	https://doi.org/10.1080/10587250210760
Publication status	Published - 2002
Event	Proceedings of the Interdisciplinary Symposium on Multifunctionality of Inorganic , Organic, and Their Hybrid Solids - Honolulu, HI, United States Duration: 2000 Dec 15 → 2000 Dec 18

Keywords

Nitridochromium(V) complex
Nitridomanganese(V) complex
Polymeric structure

ASJC Scopus subject areas

Condensed Matter Physics

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10.1080/10587250210760

Cite this

Synthesis and crystal structures of polymeric nitridomanganese(V) and nitridochromium(V) complexes with a tetradentate schiff base ligand. / Tsuchimoto, Masanobu; Iwamoto, Hirofumi; Kojima, Masaaki et al.
In: Molecular Crystals and Liquid Crystals Science and Technology, Section A: Molecular Crystals and Liquid Crystals, Vol. 376, 2002, p. 33-38.

Research output: Contribution to journal › Conference article › peer-review

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title = "Synthesis and crystal structures of polymeric nitridomanganese(V) and nitridochromium(V) complexes with a tetradentate schiff base ligand",

abstract = "Novel polymeric nitridomanganese(V) and nitridochromium(V) complexes with a Schiff base ligand, [MnN(salpn)] and [CrN(salpn)] (H2(salpn): N,N'-disalicylidene-1,3-propanediamine) were prepared by photolysis of azido complexes. X-ray crystal structure analyses show that the complexes have an isostructual polymeric structure (⋯M≡N⋯M≡N⋯) with the N⋯M distances being 2.528(3) {\AA} for M=Mn, and 2.508(2) {\AA} for M=Cr.",

keywords = "Nitridochromium(V) complex, Nitridomanganese(V) complex, Polymeric structure",

author = "Masanobu Tsuchimoto and Hirofumi Iwamoto and Masaaki Kojima and Shigeru Ohba",

year = "2002",

doi = "10.1080/10587250210760",

language = "English",

volume = "376",

pages = "33--38",

journal = "Molecular Crystals and Liquid Crystals Science and Technology, Section A: Molecular Crystals and Liquid Crystals",

issn = "1058-725X",

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note = "Proceedings of the Interdisciplinary Symposium on Multifunctionality of Inorganic , Organic, and Their Hybrid Solids ; Conference date: 15-12-2000 Through 18-12-2000",

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AU - Tsuchimoto, Masanobu

AU - Iwamoto, Hirofumi

AU - Kojima, Masaaki

AU - Ohba, Shigeru

PY - 2002

Y1 - 2002

N2 - Novel polymeric nitridomanganese(V) and nitridochromium(V) complexes with a Schiff base ligand, [MnN(salpn)] and [CrN(salpn)] (H2(salpn): N,N'-disalicylidene-1,3-propanediamine) were prepared by photolysis of azido complexes. X-ray crystal structure analyses show that the complexes have an isostructual polymeric structure (⋯M≡N⋯M≡N⋯) with the N⋯M distances being 2.528(3) Å for M=Mn, and 2.508(2) Å for M=Cr.

AB - Novel polymeric nitridomanganese(V) and nitridochromium(V) complexes with a Schiff base ligand, [MnN(salpn)] and [CrN(salpn)] (H2(salpn): N,N'-disalicylidene-1,3-propanediamine) were prepared by photolysis of azido complexes. X-ray crystal structure analyses show that the complexes have an isostructual polymeric structure (⋯M≡N⋯M≡N⋯) with the N⋯M distances being 2.528(3) Å for M=Mn, and 2.508(2) Å for M=Cr.

KW - Nitridochromium(V) complex

KW - Nitridomanganese(V) complex

KW - Polymeric structure

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U2 - 10.1080/10587250210760

DO - 10.1080/10587250210760

M3 - Conference article

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SN - 1058-725X

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SP - 33

EP - 38

JO - Molecular Crystals and Liquid Crystals Science and Technology, Section A: Molecular Crystals and Liquid Crystals

JF - Molecular Crystals and Liquid Crystals Science and Technology, Section A: Molecular Crystals and Liquid Crystals

T2 - Proceedings of the Interdisciplinary Symposium on Multifunctionality of Inorganic , Organic, and Their Hybrid Solids

Y2 - 15 December 2000 through 18 December 2000

ER -

Synthesis and crystal structures of polymeric nitridomanganese(V) and nitridochromium(V) complexes with a tetradentate schiff base ligand

Abstract

Keywords

ASJC Scopus subject areas

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