TY - JOUR
T1 - Synthesis and properties of the 3-tert-butyl-7-trifluoromethyl-1,4-dihydro-1-phenyl-1,2,4-benzotriazin-4-yl radical
AU - Takahashi, Yusuke
AU - Miura, Youhei
AU - Yoshioka, Naoki
N1 - Publisher Copyright:
© The Royal Society of Chemistry and the Centre National de la Recherche Scientifique.
PY - 2015/6/1
Y1 - 2015/6/1
N2 - A novel benzotriazinyl radical, 3-tert-butyl-7-trifluoromethyl-1,4-dihydro-1-phenyl-1,2,4-benzotriazin-4-yl (2), was prepared and its magneto-structural correlation was investigated. An X-ray crystallographic analysis revealed that 2 forms a 1D column assembly, however, π-π interaction was not the driving force of the column structure. The magnetic susceptibility obeyed the Curie-Weiss law with C = 0.369 emu K mol-1 and = +0.7 K. The thermal behavior of χmT was described using the 1D ferromagnetic chain model with J/kB = +0.91 K.
AB - A novel benzotriazinyl radical, 3-tert-butyl-7-trifluoromethyl-1,4-dihydro-1-phenyl-1,2,4-benzotriazin-4-yl (2), was prepared and its magneto-structural correlation was investigated. An X-ray crystallographic analysis revealed that 2 forms a 1D column assembly, however, π-π interaction was not the driving force of the column structure. The magnetic susceptibility obeyed the Curie-Weiss law with C = 0.369 emu K mol-1 and = +0.7 K. The thermal behavior of χmT was described using the 1D ferromagnetic chain model with J/kB = +0.91 K.
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U2 - 10.1039/c5nj00393h
DO - 10.1039/c5nj00393h
M3 - Article
AN - SCOPUS:84930646166
SN - 1144-0546
VL - 39
SP - 4783
EP - 4789
JO - New Journal of Chemistry
JF - New Journal of Chemistry
IS - 6
ER -