Synthesis of an extended hexagonal molecule as a highly symmetrical ligand

Masayoshi Takase; Atsushi Nakajima; Toshifumi Takeuchi

doi:10.1016/j.tetlet.2005.01.014

Synthesis of an extended hexagonal molecule as a highly symmetrical ligand

Masayoshi Takase, Atsushi Nakajima, Toshifumi Takeuchi

Research output: Contribution to journal › Article › peer-review

8 Citations (Scopus)

Abstract

An extended hexagonal molecule that has high symmetry and rigidity was designed and synthesized by a cobalt-catalyzed cyclotrimerization reaction. The ligand possesses six benzoic acids at its periphery, which were connected to a central hexakis(2,5-dodesyloxyphenyl)hexaphenylbenzene core with a maximum intramolecular carboxyl group distance of approximately 3.5 nm.

Original language	English
Pages (from-to)	1739-1742
Number of pages	4
Journal	Tetrahedron Letters
Volume	46
Issue number	10
DOIs	https://doi.org/10.1016/j.tetlet.2005.01.014
Publication status	Published - 2005 Mar 7
Externally published	Yes

Keywords

Cyclotrimerization
Hexagonal ligand
Supramolecular chemistry
Tin porphyrin

ASJC Scopus subject areas

Biochemistry
Drug Discovery
Organic Chemistry

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10.1016/j.tetlet.2005.01.014

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title = "Synthesis of an extended hexagonal molecule as a highly symmetrical ligand",

abstract = "An extended hexagonal molecule that has high symmetry and rigidity was designed and synthesized by a cobalt-catalyzed cyclotrimerization reaction. The ligand possesses six benzoic acids at its periphery, which were connected to a central hexakis(2,5-dodesyloxyphenyl)hexaphenylbenzene core with a maximum intramolecular carboxyl group distance of approximately 3.5 nm.",

keywords = "Cyclotrimerization, Hexagonal ligand, Supramolecular chemistry, Tin porphyrin",

author = "Masayoshi Takase and Atsushi Nakajima and Toshifumi Takeuchi",

note = "Funding Information: The authors gratefully acknowledged the useful discussions and the help of preparing this manuscript received from Professor Ken D. Shimizu (University of South Carolina). This work was partly supported by Mitsubishi Chemical Corporation Fund (M.T.). ",

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doi = "10.1016/j.tetlet.2005.01.014",

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journal = "Tetrahedron Letters",

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T1 - Synthesis of an extended hexagonal molecule as a highly symmetrical ligand

AU - Takase, Masayoshi

AU - Nakajima, Atsushi

AU - Takeuchi, Toshifumi

N1 - Funding Information: The authors gratefully acknowledged the useful discussions and the help of preparing this manuscript received from Professor Ken D. Shimizu (University of South Carolina). This work was partly supported by Mitsubishi Chemical Corporation Fund (M.T.).

PY - 2005/3/7

Y1 - 2005/3/7

N2 - An extended hexagonal molecule that has high symmetry and rigidity was designed and synthesized by a cobalt-catalyzed cyclotrimerization reaction. The ligand possesses six benzoic acids at its periphery, which were connected to a central hexakis(2,5-dodesyloxyphenyl)hexaphenylbenzene core with a maximum intramolecular carboxyl group distance of approximately 3.5 nm.

AB - An extended hexagonal molecule that has high symmetry and rigidity was designed and synthesized by a cobalt-catalyzed cyclotrimerization reaction. The ligand possesses six benzoic acids at its periphery, which were connected to a central hexakis(2,5-dodesyloxyphenyl)hexaphenylbenzene core with a maximum intramolecular carboxyl group distance of approximately 3.5 nm.

KW - Cyclotrimerization

KW - Hexagonal ligand

KW - Supramolecular chemistry

KW - Tin porphyrin

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DO - 10.1016/j.tetlet.2005.01.014

M3 - Article

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SN - 0040-4039

VL - 46

SP - 1739

EP - 1742

JO - Tetrahedron Letters

JF - Tetrahedron Letters

IS - 10

ER -

Synthesis of an extended hexagonal molecule as a highly symmetrical ligand

Abstract

Keywords

ASJC Scopus subject areas

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