Synthesis of N-heterocyclic carbene-sulfonate palladium complexes

Yusuke Nagai; Takuya Kochi; Kyoko Nozaki

doi:10.1021/om9004252

Synthesis of N-heterocyclic carbene-sulfonate palladium complexes

Yusuke Nagai, Takuya Kochi, Kyoko Nozaki

Research output: Contribution to journal › Article › peer-review

60 Citations (Scopus)

Abstract

Syntheses of new NHC-sulfonate palladium complexes [N-(2,6- diisopropylphenyl)-N'-sulfomethylNHC] Pd(2,6-lutidine) (7a) and [N-(2,6-diisopropylpheny I)-N' -SulfomethylNHC]Pd(PPhs₃) (7b) are reported. The structure of complexes 7a and 7b were determined by single-crystal X-ray analysis as the first examples of bidentate coordination of imidazolium-sulfonate to a metal center.

Original language	English
Pages (from-to)	6131-6134
Number of pages	4
Journal	Organometallics
Volume	28
Issue number	20
DOIs	https://doi.org/10.1021/om9004252
Publication status	Published - 2009 Oct 26
Externally published	Yes

ASJC Scopus subject areas

Physical and Theoretical Chemistry
Organic Chemistry
Inorganic Chemistry

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10.1021/om9004252

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abstract = "Syntheses of new NHC-sulfonate palladium complexes [N-(2,6- diisopropylphenyl)-N'-sulfomethylNHC] Pd(2,6-lutidine) (7a) and [N-(2,6-diisopropylpheny I)-N' -SulfomethylNHC]Pd(PPhs3) (7b) are reported. The structure of complexes 7a and 7b were determined by single-crystal X-ray analysis as the first examples of bidentate coordination of imidazolium-sulfonate to a metal center.",

author = "Yusuke Nagai and Takuya Kochi and Kyoko Nozaki",

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T1 - Synthesis of N-heterocyclic carbene-sulfonate palladium complexes

AU - Nagai, Yusuke

AU - Kochi, Takuya

AU - Nozaki, Kyoko

PY - 2009/10/26

Y1 - 2009/10/26

N2 - Syntheses of new NHC-sulfonate palladium complexes [N-(2,6- diisopropylphenyl)-N'-sulfomethylNHC] Pd(2,6-lutidine) (7a) and [N-(2,6-diisopropylpheny I)-N' -SulfomethylNHC]Pd(PPhs3) (7b) are reported. The structure of complexes 7a and 7b were determined by single-crystal X-ray analysis as the first examples of bidentate coordination of imidazolium-sulfonate to a metal center.

AB - Syntheses of new NHC-sulfonate palladium complexes [N-(2,6- diisopropylphenyl)-N'-sulfomethylNHC] Pd(2,6-lutidine) (7a) and [N-(2,6-diisopropylpheny I)-N' -SulfomethylNHC]Pd(PPhs3) (7b) are reported. The structure of complexes 7a and 7b were determined by single-crystal X-ray analysis as the first examples of bidentate coordination of imidazolium-sulfonate to a metal center.

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ER -

Synthesis of N-heterocyclic carbene-sulfonate palladium complexes

Abstract

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