Synthesis of the ABC ring fragment of brevisin, a new dinoflagellate polycyclic ether

Naohito Ohtani; Ryosuke Tsutsumi; Takefumi Kuranaga; Tomohiro Shirai; Jeffrey L.C. Wright; Daniel G. Baden; Masayuki Satake; Kazuo Tachibana

doi:10.3987/COM-09-S(S)93

Synthesis of the ABC ring fragment of brevisin, a new dinoflagellate polycyclic ether

Naohito Ohtani, Ryosuke Tsutsumi, Takefumi Kuranaga, Tomohiro Shirai, Jeffrey L.C. Wright, Daniel G. Baden, Masayuki Satake, Kazuo Tachibana

Research output: Contribution to journal › Article › peer-review

7 Citations (Scopus)

Abstract

A polycyclic ether, brevisin was isolated from the red-tide dinoflagellate Karenia brevis. Its unique skeletal structure consists of two separate tricyclic ether assemblies connected by a methylene bridge. The ABC ring fragment of brevisin was synthesized via Suzuki-Miyaura cross coupling toward a total synthesis of brevisin.

Original language	English
Pages (from-to)	825-830
Number of pages	6
Journal	Heterocycles
Volume	80
Issue number	2
DOIs	https://doi.org/10.3987/COM-09-S(S)93
Publication status	Published - 2010 Mar 1
Externally published	Yes

Keywords

Ketene Acetal Phosphate
Polycyclic Ether
Suzuki-Miyaura Cross Coupling Reaction

ASJC Scopus subject areas

Analytical Chemistry
Pharmacology
Organic Chemistry

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10.3987/COM-09-S(S)93

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title = "Synthesis of the ABC ring fragment of brevisin, a new dinoflagellate polycyclic ether",

abstract = "A polycyclic ether, brevisin was isolated from the red-tide dinoflagellate Karenia brevis. Its unique skeletal structure consists of two separate tricyclic ether assemblies connected by a methylene bridge. The ABC ring fragment of brevisin was synthesized via Suzuki-Miyaura cross coupling toward a total synthesis of brevisin.",

keywords = "Ketene Acetal Phosphate, Polycyclic Ether, Suzuki-Miyaura Cross Coupling Reaction",

author = "Naohito Ohtani and Ryosuke Tsutsumi and Takefumi Kuranaga and Tomohiro Shirai and Wright, {Jeffrey L.C.} and Baden, {Daniel G.} and Masayuki Satake and Kazuo Tachibana",

year = "2010",

month = mar,

day = "1",

doi = "10.3987/COM-09-S(S)93",

language = "English",

volume = "80",

pages = "825--830",

journal = "Heterocycles",

issn = "0385-5414",

publisher = "Japan Institute of Heterocyclic Chemistry",

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TY - JOUR

T1 - Synthesis of the ABC ring fragment of brevisin, a new dinoflagellate polycyclic ether

AU - Ohtani, Naohito

AU - Tsutsumi, Ryosuke

AU - Kuranaga, Takefumi

AU - Shirai, Tomohiro

AU - Wright, Jeffrey L.C.

AU - Baden, Daniel G.

AU - Satake, Masayuki

AU - Tachibana, Kazuo

PY - 2010/3/1

Y1 - 2010/3/1

N2 - A polycyclic ether, brevisin was isolated from the red-tide dinoflagellate Karenia brevis. Its unique skeletal structure consists of two separate tricyclic ether assemblies connected by a methylene bridge. The ABC ring fragment of brevisin was synthesized via Suzuki-Miyaura cross coupling toward a total synthesis of brevisin.

AB - A polycyclic ether, brevisin was isolated from the red-tide dinoflagellate Karenia brevis. Its unique skeletal structure consists of two separate tricyclic ether assemblies connected by a methylene bridge. The ABC ring fragment of brevisin was synthesized via Suzuki-Miyaura cross coupling toward a total synthesis of brevisin.

KW - Ketene Acetal Phosphate

KW - Polycyclic Ether

KW - Suzuki-Miyaura Cross Coupling Reaction

UR - http://www.scopus.com/inward/record.url?scp=77955665001&partnerID=8YFLogxK

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U2 - 10.3987/COM-09-S(S)93

DO - 10.3987/COM-09-S(S)93

M3 - Article

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SN - 0385-5414

VL - 80

SP - 825

EP - 830

JO - Heterocycles

JF - Heterocycles

IS - 2

ER -

Synthesis of the ABC ring fragment of brevisin, a new dinoflagellate polycyclic ether

Abstract

Keywords

ASJC Scopus subject areas

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