Synthetic application of PVP-stabilized Au nanocluster catalyst to aerobic oxidation of alcohols in aqueous solution under ambient conditions

Hironori Tsunoyama; Tatsuya Tsukuda; Hidehiro Sakurai

doi:10.1246/cl.2007.212

Synthetic application of PVP-stabilized Au nanocluster catalyst to aerobic oxidation of alcohols in aqueous solution under ambient conditions

Hironori Tsunoyama, Tatsuya Tsukuda, Hidehiro Sakurai

Research output: Contribution to journal › Article › peer-review

81 Citations (Scopus)

Abstract

Gold nanoclusters (φ = 1.3 nm) stabilized by poly(N-vinyl-2- pyrrolidone) (Au:PVP) were found to show a high catalytic activity toward the aerobic oxidation of alcohols. Various kinds of primary and secondary alcohols were converted to the corresponding carboxylic acids and ketones, respectively, in basic aqueous media at 300-360 K under air.

Original language	English
Pages (from-to)	212-213
Number of pages	2
Journal	Chemistry Letters
Volume	36
Issue number	2
DOIs	https://doi.org/10.1246/cl.2007.212
Publication status	Published - 2007 Feb 5
Externally published	Yes

ASJC Scopus subject areas

Chemistry(all)

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10.1246/cl.2007.212

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abstract = "Gold nanoclusters (φ = 1.3 nm) stabilized by poly(N-vinyl-2- pyrrolidone) (Au:PVP) were found to show a high catalytic activity toward the aerobic oxidation of alcohols. Various kinds of primary and secondary alcohols were converted to the corresponding carboxylic acids and ketones, respectively, in basic aqueous media at 300-360 K under air.",

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AU - Sakurai, Hidehiro

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AB - Gold nanoclusters (φ = 1.3 nm) stabilized by poly(N-vinyl-2- pyrrolidone) (Au:PVP) were found to show a high catalytic activity toward the aerobic oxidation of alcohols. Various kinds of primary and secondary alcohols were converted to the corresponding carboxylic acids and ketones, respectively, in basic aqueous media at 300-360 K under air.

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Synthetic application of PVP-stabilized Au nanocluster catalyst to aerobic oxidation of alcohols in aqueous solution under ambient conditions

Abstract

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