Synthetic application of PVP-stabilized Au nanocluster catalyst to aerobic oxidation of alcohols in aqueous solution under ambient conditions

Hironori Tsunoyama; Tatsuya Tsukuda; Hidehiro Sakurai

doi:10.1246/cl.2007.212

Synthetic application of PVP-stabilized Au nanocluster catalyst to aerobic oxidation of alcohols in aqueous solution under ambient conditions

Hironori Tsunoyama
, Tatsuya Tsukuda
, Hidehiro Sakurai

Research output: Contribution to journal › Article › peer-review

83 Citations (Scopus)

Abstract

Gold nanoclusters (φ = 1.3 nm) stabilized by poly(N-vinyl-2- pyrrolidone) (Au:PVP) were found to show a high catalytic activity toward the aerobic oxidation of alcohols. Various kinds of primary and secondary alcohols were converted to the corresponding carboxylic acids and ketones, respectively, in basic aqueous media at 300-360 K under air.

Original language	English
Pages (from-to)	212-213
Number of pages	2
Journal	Chemistry Letters
Volume	36
Issue number	2
DOIs	https://doi.org/10.1246/cl.2007.212
Publication status	Published - 2007 Feb 5
Externally published	Yes

ASJC Scopus subject areas

General Chemistry

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10.1246/cl.2007.212

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title = "Synthetic application of PVP-stabilized Au nanocluster catalyst to aerobic oxidation of alcohols in aqueous solution under ambient conditions",

abstract = "Gold nanoclusters (φ = 1.3 nm) stabilized by poly(N-vinyl-2- pyrrolidone) (Au:PVP) were found to show a high catalytic activity toward the aerobic oxidation of alcohols. Various kinds of primary and secondary alcohols were converted to the corresponding carboxylic acids and ketones, respectively, in basic aqueous media at 300-360 K under air.",

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AU - Tsukuda, Tatsuya

AU - Sakurai, Hidehiro

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Y1 - 2007/2/5

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AB - Gold nanoclusters (φ = 1.3 nm) stabilized by poly(N-vinyl-2- pyrrolidone) (Au:PVP) were found to show a high catalytic activity toward the aerobic oxidation of alcohols. Various kinds of primary and secondary alcohols were converted to the corresponding carboxylic acids and ketones, respectively, in basic aqueous media at 300-360 K under air.

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JO - Chemistry Letters

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ER -

Synthetic application of PVP-stabilized Au nanocluster catalyst to aerobic oxidation of alcohols in aqueous solution under ambient conditions

Abstract

ASJC Scopus subject areas

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