The electrooxidation of sulfur-containing compounds at boron-doped diamond electrode

O. Chailapakul; P. Aksharanandana; T. Frelink; Y. Einaga; A. Fujishima

doi:10.1016/S0925-4005(01)00912-1

The electrooxidation of sulfur-containing compounds at boron-doped diamond electrode

O. Chailapakul, P. Aksharanandana, T. Frelink, Y. Einaga, A. Fujishima

Research output: Contribution to journal › Article › peer-review

68 Citations (Scopus)

Abstract

The electrooxidation of homocysteine, glutathione (GSH), 2-mercapto ethanesulfonic acid and cephalexin at boron-doped diamond (BDD) electrodes and glassy carbon (GC) electrodes was investigated by cyclic voltammetry. The oxidation of these sulfur-containing compounds exhibited well-defined irreversible responses. This preliminary study has shown that BDD has better sensitivity than GC. Concentration dependence has been studied and indicated the promise of using BDD electrodes for quantitative determination. All of the compounds displayed recognizable oxidation peaks at BDD electrodes at millimolar concentration levels. Scan rate dependence of GSH has been examined. It was shown that there was no adsorption on the surface of the BDD electrode for the low concentration.

Original language	English
Pages (from-to)	193-201
Number of pages	9
Journal	Sensors and Actuators, B: Chemical
Volume	80
Issue number	3
DOIs	https://doi.org/10.1016/S0925-4005(01)00912-1
Publication status	Published - 2001 Dec 1
Externally published	Yes

Keywords

2-Mercapto ethanesulfonic acid
Cephalexin
Diamond electrodes
Electrochemistry
Glutathione
Homocysteine

ASJC Scopus subject areas

Electronic, Optical and Magnetic Materials
Instrumentation
Condensed Matter Physics
Surfaces, Coatings and Films
Metals and Alloys
Electrical and Electronic Engineering
Materials Chemistry

Access to Document

10.1016/S0925-4005(01)00912-1

Cite this

@article{68622224c284472186667f10d44da6d9,

title = "The electrooxidation of sulfur-containing compounds at boron-doped diamond electrode",

abstract = "The electrooxidation of homocysteine, glutathione (GSH), 2-mercapto ethanesulfonic acid and cephalexin at boron-doped diamond (BDD) electrodes and glassy carbon (GC) electrodes was investigated by cyclic voltammetry. The oxidation of these sulfur-containing compounds exhibited well-defined irreversible responses. This preliminary study has shown that BDD has better sensitivity than GC. Concentration dependence has been studied and indicated the promise of using BDD electrodes for quantitative determination. All of the compounds displayed recognizable oxidation peaks at BDD electrodes at millimolar concentration levels. Scan rate dependence of GSH has been examined. It was shown that there was no adsorption on the surface of the BDD electrode for the low concentration.",

keywords = "2-Mercapto ethanesulfonic acid, Cephalexin, Diamond electrodes, Electrochemistry, Glutathione, Homocysteine",

author = "O. Chailapakul and P. Aksharanandana and T. Frelink and Y. Einaga and A. Fujishima",

year = "2001",

month = dec,

day = "1",

doi = "10.1016/S0925-4005(01)00912-1",

language = "English",

volume = "80",

pages = "193--201",

journal = "Sensors and Actuators, B: Chemical",

issn = "0925-4005",

publisher = "Elsevier",

number = "3",

}

TY - JOUR

T1 - The electrooxidation of sulfur-containing compounds at boron-doped diamond electrode

AU - Chailapakul, O.

AU - Aksharanandana, P.

AU - Frelink, T.

AU - Einaga, Y.

AU - Fujishima, A.

PY - 2001/12/1

Y1 - 2001/12/1

N2 - The electrooxidation of homocysteine, glutathione (GSH), 2-mercapto ethanesulfonic acid and cephalexin at boron-doped diamond (BDD) electrodes and glassy carbon (GC) electrodes was investigated by cyclic voltammetry. The oxidation of these sulfur-containing compounds exhibited well-defined irreversible responses. This preliminary study has shown that BDD has better sensitivity than GC. Concentration dependence has been studied and indicated the promise of using BDD electrodes for quantitative determination. All of the compounds displayed recognizable oxidation peaks at BDD electrodes at millimolar concentration levels. Scan rate dependence of GSH has been examined. It was shown that there was no adsorption on the surface of the BDD electrode for the low concentration.

AB - The electrooxidation of homocysteine, glutathione (GSH), 2-mercapto ethanesulfonic acid and cephalexin at boron-doped diamond (BDD) electrodes and glassy carbon (GC) electrodes was investigated by cyclic voltammetry. The oxidation of these sulfur-containing compounds exhibited well-defined irreversible responses. This preliminary study has shown that BDD has better sensitivity than GC. Concentration dependence has been studied and indicated the promise of using BDD electrodes for quantitative determination. All of the compounds displayed recognizable oxidation peaks at BDD electrodes at millimolar concentration levels. Scan rate dependence of GSH has been examined. It was shown that there was no adsorption on the surface of the BDD electrode for the low concentration.

KW - 2-Mercapto ethanesulfonic acid

KW - Cephalexin

KW - Diamond electrodes

KW - Electrochemistry

KW - Glutathione

KW - Homocysteine

UR - http://www.scopus.com/inward/record.url?scp=0035545729&partnerID=8YFLogxK

UR - http://www.scopus.com/inward/citedby.url?scp=0035545729&partnerID=8YFLogxK

U2 - 10.1016/S0925-4005(01)00912-1

DO - 10.1016/S0925-4005(01)00912-1

M3 - Article

AN - SCOPUS:0035545729

SN - 0925-4005

VL - 80

SP - 193

EP - 201

JO - Sensors and Actuators, B: Chemical

JF - Sensors and Actuators, B: Chemical

IS - 3

ER -

The electrooxidation of sulfur-containing compounds at boron-doped diamond electrode

Abstract

Keywords

ASJC Scopus subject areas

Access to Document

Other files and links

Fingerprint

Cite this