The HfCl4-mediated Diels-Alder reaction of furan

Yujiro Hayashi; Masahiko Nakamura; Shigehiro Nakao; Tae Inoue; Mitsuru Shoji

doi:10.1002/1521-3773(20021104)41:21<4079::AID-ANIE4079>3.0.CO;2-N

The HfCl₄-mediated Diels-Alder reaction of furan

Yujiro Hayashi, Masahiko Nakamura, Shigehiro Nakao, Tae Inoue, Mitsuru Shoji

Research output: Contribution to journal › Article › peer-review

55 Citations (Scopus)

Abstract

High yields and high endo selectivity of the cycloadducts formed from the Diels-Alder reaction of furan or substituted furans occurs with an HfCl₄ catalyst (see scheme). The use of the catalyst allows reactions to be performed at low temperature under kinetic control, as shown for the highly diastereoselective Diels-Alder reaction of a chiral acrylate.

Original language	English
Pages (from-to)	4079-4082
Number of pages	4
Journal	Angewandte Chemie - International Edition
Volume	41
Issue number	21
DOIs	https://doi.org/10.1002/1521-3773(20021104)41:21<4079::AID-ANIE4079>3.0.CO;2-N
Publication status	Published - 2002 Nov 4
Externally published	Yes

Keywords

Asymmetric synthesis
Cycloaddition
Furanes
Hafnium
Pericyclic reaction

ASJC Scopus subject areas

Catalysis
Chemistry(all)

Access to Document

10.1002/1521-3773(20021104)41:21<4079::AID-ANIE4079>3.0.CO;2-N

Cite this

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abstract = "High yields and high endo selectivity of the cycloadducts formed from the Diels-Alder reaction of furan or substituted furans occurs with an HfCl4 catalyst (see scheme). The use of the catalyst allows reactions to be performed at low temperature under kinetic control, as shown for the highly diastereoselective Diels-Alder reaction of a chiral acrylate.",

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AU - Inoue, Tae

AU - Shoji, Mitsuru

PY - 2002/11/4

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