Treatment of 1,6-diyn-3-ene system 1 with SeO2 caused a Myers type cyclization to produce a biradical 6 through an enyne-allene system 5 which was generated by an ene reaction of 1 with SeO2, in analogy with the case of neocarzinostatin chromophore.
|Number of pages
|Journal of the Chemical Society, Chemical Communications
|Published - 1991 Dec 1
ASJC Scopus subject areas
- Molecular Medicine