The ruthenium-catalyzed addition of β C-H bonds in aldehydes to olefins

Fumitoshi Kakiuchi; Taisuke Sato; Kimitaka Igi; Naoto Chatani; Shinji Murai

doi:10.1246/cl.2001.386

The ruthenium-catalyzed addition of β C-H bonds in aldehydes to olefins

Fumitoshi Kakiuchi, Taisuke Sato, Kimitaka Igi, Naoto Chatani, Shinji Murai

Research output: Contribution to journal › Article › peer-review

92 Citations (Scopus)

Abstract

The addition of a β C-H bond to the formyl group of aldehydes to olefins took place with the aid of Ru(H)₂(CO)(PPh₃)₃ as a catalyst. Several olefins can be used in the catalytic reaction of conjugate enals. The presence of a sterically hindered substituent at the ortho position of benzaldehyde and the presence of an electron donating substituent appear to be important factor in accomplishing the desired coupling reaction.

Original language	English
Pages (from-to)	386-387
Number of pages	2
Journal	Chemistry Letters
Issue number	5
DOIs	https://doi.org/10.1246/cl.2001.386
Publication status	Published - 2001
Externally published	Yes

ASJC Scopus subject areas

Chemistry(all)

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10.1246/cl.2001.386

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abstract = "The addition of a β C-H bond to the formyl group of aldehydes to olefins took place with the aid of Ru(H)2(CO)(PPh3)3 as a catalyst. Several olefins can be used in the catalytic reaction of conjugate enals. The presence of a sterically hindered substituent at the ortho position of benzaldehyde and the presence of an electron donating substituent appear to be important factor in accomplishing the desired coupling reaction.",

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AU - Sato, Taisuke

AU - Igi, Kimitaka

AU - Chatani, Naoto

AU - Murai, Shinji

PY - 2001

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AB - The addition of a β C-H bond to the formyl group of aldehydes to olefins took place with the aid of Ru(H)2(CO)(PPh3)3 as a catalyst. Several olefins can be used in the catalytic reaction of conjugate enals. The presence of a sterically hindered substituent at the ortho position of benzaldehyde and the presence of an electron donating substituent appear to be important factor in accomplishing the desired coupling reaction.

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The ruthenium-catalyzed addition of β C-H bonds in aldehydes to olefins

Abstract

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