The ruthenium-catalyzed addition of C-H bonds in aromatic nitriles to olefins

Fumitoshi Kakiuchi; Motohiro Sonoda; Takuya Tsujimoto; Naoto Chatani; Shinji Murai

doi:10.1246/cl.1999.1083

The ruthenium-catalyzed addition of C-H bonds in aromatic nitriles to olefins

Fumitoshi Kakiuchi, Motohiro Sonoda, Takuya Tsujimoto, Naoto Chatani, Shinji Murai

Research output: Contribution to journal › Article › peer-review

88 Citations (Scopus)

Abstract

The reaction of aromatic nitriles with triethoxyvinylsilane proceeded in the presence of a Ru(H)₂(CO)(PPh₃)₃-catalyst to give the corresponding C-H/olefin coupling products in high yields. The nitrile group is capable of directing the ruthenium to the ortho C-H bond via π-bonded mode.

Original language	English
Pages (from-to)	1083-1084
Number of pages	2
Journal	Chemistry Letters
Issue number	10
DOIs	https://doi.org/10.1246/cl.1999.1083
Publication status	Published - 1999 Jan 1
Externally published	Yes

ASJC Scopus subject areas

Chemistry(all)

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10.1246/cl.1999.1083

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title = "The ruthenium-catalyzed addition of C-H bonds in aromatic nitriles to olefins",

abstract = "The reaction of aromatic nitriles with triethoxyvinylsilane proceeded in the presence of a Ru(H)2(CO)(PPh3)3-catalyst to give the corresponding C-H/olefin coupling products in high yields. The nitrile group is capable of directing the ruthenium to the ortho C-H bond via π-bonded mode.",

author = "Fumitoshi Kakiuchi and Motohiro Sonoda and Takuya Tsujimoto and Naoto Chatani and Shinji Murai",

year = "1999",

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T1 - The ruthenium-catalyzed addition of C-H bonds in aromatic nitriles to olefins

AU - Kakiuchi, Fumitoshi

AU - Sonoda, Motohiro

AU - Tsujimoto, Takuya

AU - Chatani, Naoto

AU - Murai, Shinji

PY - 1999/1/1

Y1 - 1999/1/1

N2 - The reaction of aromatic nitriles with triethoxyvinylsilane proceeded in the presence of a Ru(H)2(CO)(PPh3)3-catalyst to give the corresponding C-H/olefin coupling products in high yields. The nitrile group is capable of directing the ruthenium to the ortho C-H bond via π-bonded mode.

AB - The reaction of aromatic nitriles with triethoxyvinylsilane proceeded in the presence of a Ru(H)2(CO)(PPh3)3-catalyst to give the corresponding C-H/olefin coupling products in high yields. The nitrile group is capable of directing the ruthenium to the ortho C-H bond via π-bonded mode.

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DO - 10.1246/cl.1999.1083

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The ruthenium-catalyzed addition of C-H bonds in aromatic nitriles to olefins

Abstract

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