The structure, photo-induced magnetization and correlation of the cyano-bridged two-dimensional hetero-bimetallic compounds

Guangming Li; Pengfei Yan; Osamu Sato; Yasuaki Einaga

doi:10.1016/j.jssc.2004.10.027

The structure, photo-induced magnetization and correlation of the cyano-bridged two-dimensional hetero-bimetallic compounds

Guangming Li, Pengfei Yan, Osamu Sato, Yasuaki Einaga

Department of Chemistry

Research output: Contribution to journal › Article › peer-review

17 Citations (Scopus)

Abstract

Two new 3d-4f cyano-bridged hetero-bimetallic compounds with distinguished two-dimensional honeycomb network structure, {Ln(HP)₂(H ₂O)₃(μ-NC)₃Fe(CN)₃}_n, (Ln=Ce, Nd; HP=4-Hydroxypyridine) were synthesized and crystallographically characterized. A novel photo-induced magnetization phenomenon for {Nd(HP) ₂(H₂O)₃(μ-NC)₃Fe(CN) ₃}_n, was revealed and studied. Furthermore, the correlation between photo-induced magnetization and structure was proposed.

Original language	English
Pages (from-to)	36-40
Number of pages	5
Journal	Journal of Solid State Chemistry
Volume	178
Issue number	1
DOIs	https://doi.org/10.1016/j.jssc.2004.10.027
Publication status	Published - 2005 Jan

Keywords

Crystal structure
Cyano-bridged
Iron
Lanthanide metal
Photo-induced magnetization

ASJC Scopus subject areas

Electronic, Optical and Magnetic Materials
Ceramics and Composites
Condensed Matter Physics
Physical and Theoretical Chemistry
Inorganic Chemistry
Materials Chemistry

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10.1016/j.jssc.2004.10.027

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title = "The structure, photo-induced magnetization and correlation of the cyano-bridged two-dimensional hetero-bimetallic compounds",

abstract = "Two new 3d-4f cyano-bridged hetero-bimetallic compounds with distinguished two-dimensional honeycomb network structure, {Ln(HP)2(H 2O)3(μ-NC)3Fe(CN)3}n, (Ln=Ce, Nd; HP=4-Hydroxypyridine) were synthesized and crystallographically characterized. A novel photo-induced magnetization phenomenon for {Nd(HP) 2(H2O)3(μ-NC)3Fe(CN) 3}n, was revealed and studied. Furthermore, the correlation between photo-induced magnetization and structure was proposed.",

keywords = "Crystal structure, Cyano-bridged, Iron, Lanthanide metal, Photo-induced magnetization",

author = "Guangming Li and Pengfei Yan and Osamu Sato and Yasuaki Einaga",

note = "Funding Information: This work is supported by Grant-in-Aid for Scientific Research on Priority Areas (417) and for the 21st century COE program “Keio Life Conjugate Chemistry” from the Ministry of Education, Culture, Sport, Science, and Technology (MEXT) of Japan.",

year = "2005",

month = jan,

doi = "10.1016/j.jssc.2004.10.027",

language = "English",

volume = "178",

pages = "36--40",

journal = "Journal of Solid State Chemistry",

issn = "0022-4596",

publisher = "Academic Press Inc.",

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T1 - The structure, photo-induced magnetization and correlation of the cyano-bridged two-dimensional hetero-bimetallic compounds

AU - Li, Guangming

AU - Yan, Pengfei

AU - Sato, Osamu

AU - Einaga, Yasuaki

N1 - Funding Information: This work is supported by Grant-in-Aid for Scientific Research on Priority Areas (417) and for the 21st century COE program “Keio Life Conjugate Chemistry” from the Ministry of Education, Culture, Sport, Science, and Technology (MEXT) of Japan.

PY - 2005/1

Y1 - 2005/1

N2 - Two new 3d-4f cyano-bridged hetero-bimetallic compounds with distinguished two-dimensional honeycomb network structure, {Ln(HP)2(H 2O)3(μ-NC)3Fe(CN)3}n, (Ln=Ce, Nd; HP=4-Hydroxypyridine) were synthesized and crystallographically characterized. A novel photo-induced magnetization phenomenon for {Nd(HP) 2(H2O)3(μ-NC)3Fe(CN) 3}n, was revealed and studied. Furthermore, the correlation between photo-induced magnetization and structure was proposed.

AB - Two new 3d-4f cyano-bridged hetero-bimetallic compounds with distinguished two-dimensional honeycomb network structure, {Ln(HP)2(H 2O)3(μ-NC)3Fe(CN)3}n, (Ln=Ce, Nd; HP=4-Hydroxypyridine) were synthesized and crystallographically characterized. A novel photo-induced magnetization phenomenon for {Nd(HP) 2(H2O)3(μ-NC)3Fe(CN) 3}n, was revealed and studied. Furthermore, the correlation between photo-induced magnetization and structure was proposed.

KW - Crystal structure

KW - Cyano-bridged

KW - Iron

KW - Lanthanide metal

KW - Photo-induced magnetization

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DO - 10.1016/j.jssc.2004.10.027

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AN - SCOPUS:13544249971

SN - 0022-4596

VL - 178

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JO - Journal of Solid State Chemistry

JF - Journal of Solid State Chemistry

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The structure, photo-induced magnetization and correlation of the cyano-bridged two-dimensional hetero-bimetallic compounds

Abstract

Keywords

ASJC Scopus subject areas

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