Thermal and Photo-Responsibility of Axial Semi-Coordination Bonds in a Copper(II) Complex

Takashiro Akitsu; Yasuaki Einaga

doi:10.1246/bcsj.77.763

Thermal and Photo-Responsibility of Axial Semi-Coordination Bonds in a Copper(II) Complex

Takashiro Akitsu, Yasuaki Einaga

Department of Chemistry

Research output: Contribution to journal › Article › peer-review

12 Citations (Scopus)

Abstract

The thermal and photo-responsibility of the axial semicoordination Cu-O bonds in [Cu(en)₂](ClO₄)₂ (1) (en = ethylenediamine) have been investigated. We discovered a new photoresponsive behavior that was attributed to photoinduced ClO₄^- cleavage accompanied by compression of the Cu-O bonds using the structural degree of freedom of the semi-coordination bonds.

Original language	English
Pages (from-to)	763-764
Number of pages	2
Journal	Bulletin of the Chemical Society of Japan
Volume	77
Issue number	4
DOIs	https://doi.org/10.1246/bcsj.77.763
Publication status	Published - 2004

ASJC Scopus subject areas

Chemistry(all)

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10.1246/bcsj.77.763

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abstract = "The thermal and photo-responsibility of the axial semicoordination Cu-O bonds in [Cu(en)2](ClO4)2 (1) (en = ethylenediamine) have been investigated. We discovered a new photoresponsive behavior that was attributed to photoinduced ClO4- cleavage accompanied by compression of the Cu-O bonds using the structural degree of freedom of the semi-coordination bonds.",

author = "Takashiro Akitsu and Yasuaki Einaga",

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AB - The thermal and photo-responsibility of the axial semicoordination Cu-O bonds in [Cu(en)2](ClO4)2 (1) (en = ethylenediamine) have been investigated. We discovered a new photoresponsive behavior that was attributed to photoinduced ClO4- cleavage accompanied by compression of the Cu-O bonds using the structural degree of freedom of the semi-coordination bonds.

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Thermal and Photo-Responsibility of Axial Semi-Coordination Bonds in a Copper(II) Complex

Abstract

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