Abstract
Decarboxylative Nazarov cyclization of chiral cyclic enol carbonates proceeded to afford chiral 2-cyclopentenones with excellent chirality transfer under thermal conditions without any catalyst. Interestingly, the thermal decarboxylative Nazarov cyclization furnished the desired product with better chirality transfer than the Lewis acid-catalyzed reaction.
| Original language | English |
|---|---|
| Pages (from-to) | 60-63 |
| Number of pages | 4 |
| Journal | Chemistry Letters |
| Volume | 49 |
| Issue number | 1 |
| DOIs | |
| Publication status | Published - 2020 |
Keywords
- Chirality transfer
- Decarboxylation
- Electrocyclization
ASJC Scopus subject areas
- General Chemistry
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