Thermodynamic analysis of hydrate-based refrigeration cycle

Riku Matsuura, Kosuke Watanabe, Yuji Yamauchi, Haruki Sato, Li Jen Chen, Ryo Ohmura

Research output: Contribution to journalArticlepeer-review

14 Citations (Scopus)


Clathrate hydrates (hydrates) have a larger dissociation heat than an evaporation heat of the working fluid of conventional refrigeration systems. This property can be applied to a novel refrigeration system. In this study, theoretical performance analysis of the refrigeration system utilizing hydrates as its working medium was conducted. We modeled the thermodynamic cycle of the hydrate-based refrigeration system composed of following processes: adiabatic compression, hydrate formation at high temperature, adiabatic expansion, and hydrate dissociation at low temperature. Based on the thermodynamic cycle, the coefficient of performance (COP) of the hydrate cycle was theoretically formulated with thermodynamic state functions of the working medium. Using the formula, COP was calculated on the three hydrate forming systems including HFC-32 + cyclopentane (CP) + water, Kr + CP + water, and HFC-41 + CP + water. The analysis based on the calculated results revealed that the dissociation heat of hydrates and the enthalpy change of guest gas were dominant factors to COP and polyatomic molecules would be appropriate for guest gas of hydrates. The maximum COP values on the hydrate cycle were comparable to those of the reversed Rankine cycle. The hydrate-based refrigeration system outperformed conventional refrigeration systems in terms of safety and environmental-friendliness.

Original languageEnglish
Article number119652
Publication statusPublished - 2021 Apr 1


  • Clathrate hydrate
  • Coefficient of performance
  • Refrigeration system
  • Theoretical analysis
  • Thermodynamic cycle

ASJC Scopus subject areas

  • Civil and Structural Engineering
  • Building and Construction
  • Modelling and Simulation
  • Renewable Energy, Sustainability and the Environment
  • Fuel Technology
  • Energy Engineering and Power Technology
  • Pollution
  • General Energy
  • Mechanical Engineering
  • Industrial and Manufacturing Engineering
  • Management, Monitoring, Policy and Law
  • Electrical and Electronic Engineering


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