TY - JOUR
T1 - Trans-Bis(2,2-diphenylethylamine-κN)bis(5,5-diphenylhydantoinato- κN3)copper(II) and its chloroform disolvate
AU - Akitsu, Takashiro
AU - Einaga, Yasuaki
PY - 2005/4
Y1 - 2005/4
N2 - The crystal structures of the title compounds, [Cu(C15H 11N2-O2)2(C14H 15N)2] and [Cu(C15H11N 2O2)2(C14H15N) 2]·2CHCl3, respectively, have been determined. The red disolvate complex affords a square-planar CuN4 coordination environment in which the Cu" atom lies on a centre of symmetry. The blue solvent-free complex affords a distorted square-pyramidal CuN4O coordination environment and adjacent molecules form centrosymmetric dimers. A comparison of the different crystal structures focuses on the role of the solvent molecules in supramolecular assemblies of the copper(II) complexes.
AB - The crystal structures of the title compounds, [Cu(C15H 11N2-O2)2(C14H 15N)2] and [Cu(C15H11N 2O2)2(C14H15N) 2]·2CHCl3, respectively, have been determined. The red disolvate complex affords a square-planar CuN4 coordination environment in which the Cu" atom lies on a centre of symmetry. The blue solvent-free complex affords a distorted square-pyramidal CuN4O coordination environment and adjacent molecules form centrosymmetric dimers. A comparison of the different crystal structures focuses on the role of the solvent molecules in supramolecular assemblies of the copper(II) complexes.
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U2 - 10.1107/S010827010500209X
DO - 10.1107/S010827010500209X
M3 - Article
C2 - 15805616
AN - SCOPUS:30744435830
SN - 0108-2701
VL - 61
SP - m183-m186
JO - Acta Crystallographica Section C: Crystal Structure Communications
JF - Acta Crystallographica Section C: Crystal Structure Communications
IS - 4
ER -