Transition metal-catalyzed dehydrogenative germylation of olefins with tri-n-butylgermane

Naoyuki Furukawa; Noriko Kourogi; Yoshio Seki; Fumitoshi Kakiuchi; Shinji Murai

doi:10.1021/om990336l

Transition metal-catalyzed dehydrogenative germylation of olefins with tri-n-butylgermane

Naoyuki Furukawa, Noriko Kourogi, Yoshio Seki, Fumitoshi Kakiuchi, Shinji Murai

Research output: Contribution to journal › Article › peer-review

27 Citations (Scopus)

Abstract

The catalyzed reaction of an excess of styrene with n-Bu₃GeH using several ruthenium and rhodium complexes gave the corresponding vinylgermanes (α-trin-butylgermylstyrene, (Z)-β-tri-n-butylgermylstyrene, and (E)-β-tri-n-butylgermylstyrene), which are dehydrogenative germylation products. The most effective catalyst was RU₃(CO)₁₂, whose use resulted in selective formation of the vinylgermanes in high yields.

Original language	English
Pages (from-to)	3764-3767
Number of pages	4
Journal	Organometallics
Volume	18
Issue number	18
DOIs	https://doi.org/10.1021/om990336l
Publication status	Published - 1999 Aug 30
Externally published	Yes

ASJC Scopus subject areas

Physical and Theoretical Chemistry
Organic Chemistry
Inorganic Chemistry

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10.1021/om990336l

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title = "Transition metal-catalyzed dehydrogenative germylation of olefins with tri-n-butylgermane",

abstract = "The catalyzed reaction of an excess of styrene with n-Bu3GeH using several ruthenium and rhodium complexes gave the corresponding vinylgermanes (α-trin-butylgermylstyrene, (Z)-β-tri-n-butylgermylstyrene, and (E)-β-tri-n-butylgermylstyrene), which are dehydrogenative germylation products. The most effective catalyst was RU3(CO)12, whose use resulted in selective formation of the vinylgermanes in high yields.",

author = "Naoyuki Furukawa and Noriko Kourogi and Yoshio Seki and Fumitoshi Kakiuchi and Shinji Murai",

year = "1999",

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T1 - Transition metal-catalyzed dehydrogenative germylation of olefins with tri-n-butylgermane

AU - Furukawa, Naoyuki

AU - Kourogi, Noriko

AU - Seki, Yoshio

AU - Kakiuchi, Fumitoshi

AU - Murai, Shinji

PY - 1999/8/30

Y1 - 1999/8/30

N2 - The catalyzed reaction of an excess of styrene with n-Bu3GeH using several ruthenium and rhodium complexes gave the corresponding vinylgermanes (α-trin-butylgermylstyrene, (Z)-β-tri-n-butylgermylstyrene, and (E)-β-tri-n-butylgermylstyrene), which are dehydrogenative germylation products. The most effective catalyst was RU3(CO)12, whose use resulted in selective formation of the vinylgermanes in high yields.

AB - The catalyzed reaction of an excess of styrene with n-Bu3GeH using several ruthenium and rhodium complexes gave the corresponding vinylgermanes (α-trin-butylgermylstyrene, (Z)-β-tri-n-butylgermylstyrene, and (E)-β-tri-n-butylgermylstyrene), which are dehydrogenative germylation products. The most effective catalyst was RU3(CO)12, whose use resulted in selective formation of the vinylgermanes in high yields.

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JO - Organometallics

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ER -

Transition metal-catalyzed dehydrogenative germylation of olefins with tri-n-butylgermane

Abstract

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