Ultracentrifuge-mediated Diels-Alder reaction in a two-phase system of water and chloroform

Yujiro Hayashi; Mitsuhiro Takeda; Mitsuru Shoji; Masataka Morita

doi:10.1246/cl.2007.68

Ultracentrifuge-mediated Diels-Alder reaction in a two-phase system of water and chloroform

Yujiro Hayashi, Mitsuhiro Takeda, Mitsuru Shoji, Masataka Morita

Research output: Contribution to journal › Article › peer-review

Abstract

Dramatic acceleration of the Diels-Alder reaction of acrylate ester or methacrolein with cyclopentadiene has been observed under ultracentrifugation conditions in the presence of water, when water-CHCl₃ two-phase system was employed. The Diels-Alder reaction proceeds in the lower organic phase under ultracentrifugation-induced high pressure with the upper water phase acting like a weight.

Original language	English
Pages (from-to)	68-69
Number of pages	2
Journal	Chemistry Letters
Volume	36
Issue number	1
DOIs	https://doi.org/10.1246/cl.2007.68
Publication status	Published - 2007 Jan 5
Externally published	Yes

ASJC Scopus subject areas

Chemistry(all)

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abstract = "Dramatic acceleration of the Diels-Alder reaction of acrylate ester or methacrolein with cyclopentadiene has been observed under ultracentrifugation conditions in the presence of water, when water-CHCl3 two-phase system was employed. The Diels-Alder reaction proceeds in the lower organic phase under ultracentrifugation-induced high pressure with the upper water phase acting like a weight.",

author = "Yujiro Hayashi and Mitsuhiro Takeda and Mitsuru Shoji and Masataka Morita",

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AU - Takeda, Mitsuhiro

AU - Shoji, Mitsuru

AU - Morita, Masataka

PY - 2007/1/5

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AB - Dramatic acceleration of the Diels-Alder reaction of acrylate ester or methacrolein with cyclopentadiene has been observed under ultracentrifugation conditions in the presence of water, when water-CHCl3 two-phase system was employed. The Diels-Alder reaction proceeds in the lower organic phase under ultracentrifugation-induced high pressure with the upper water phase acting like a weight.

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Ultracentrifuge-mediated Diels-Alder reaction in a two-phase system of water and chloroform

Abstract

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