@article{bac89331c38144be900499eb0a1b088c,
title = "Unprecedented chemo-enzymatic synthesis of stereochemically pure 3-acetoxy-2-methyl-2-vinylcycloalkanones",
abstract = "A new approach to 3-acetoxy-2-methyl-2-vinylcyclohexanone and 3-acetoxy-2-methyl-2-vinylcyclopentanone in stereochemically pure state, by means of a combination of yeast-catalyzed reduction and subsequent radical β-fragmentation is described.",
keywords = "Hydroxyketone, Radical β-fragmentation, Substituted cyclohexanone, Substituted cyclopentanone",
author = "Fuhshuku, {Ken Ichi} and Mina Tomita and Takeshi Sugai",
note = "Funding Information: The authors thank Professors Hideo Togo of Chiba University, Kozo Shishido of Tokushima University for their helpful discussions on the radical β-fragmentation. This work was accomplished as the 21st Century COE Program (KEIO LCC) from the Ministry of Education, Culture, Sports, Science, and Technology, Japan. This work was also supported by the collaborated program of {\textquoteleft}CREST: Creation of Functions of New Molecules and Molecular Assemblies{\textquoteright} of Japan Science and Technology Corporation, and we express our sincere thanks to Professors Keisuke Suzuki, and Takashi Matsumoto of Tokyo Institute of Technology. Part of this work was supported by Grant-in-Aid for Scientific Research (no. 14560084).",
year = "2004",
month = feb,
day = "16",
doi = "10.1016/j.tetlet.2003.12.084",
language = "English",
volume = "45",
pages = "1763--1767",
journal = "Tetrahedron Letters",
issn = "0040-4039",
publisher = "Elsevier Limited",
number = "8",
}