Unusual Electrochemical Properties of Low-Doped Boron-Doped Diamond Electrodes Containing sp2 Carbon

Jing Xu, Yasuyuki Yokota, Raymond A. Wong, Yousoo Kim, Yasuaki Einaga

Research output: Contribution to journalArticlepeer-review

53 Citations (Scopus)


Unexpected phenomena displayed by low-boron-doped diamond (BDD) electrodes are disclosed in the present work. Generally, the presence of sp2 nondiamond carbon impurities in BDD electrodes causes undesirable electrochemical properties, such as a reduced potential window and increased background current, etc. However, we found that the potential window and redox reaction in normally doped (1%) BDD and low-doped (0.1%) BDD exhibited opposite tendencies depending on the extent of sp2 carbon. Moreover, we found that contrary to the usual expectations, low-doped BDD containing sp2 carbon hinders electron transfer, whereas in line with expectations, normally doped BDD containing sp2 exhibits enhanced electron transfer. Surface analyses by X-ray/ultraviolet photoelectron spectroscopy (XPS/UPS) and electrochemical methods are utilized to explain these unusual phenomena. This work indicates that the electrochemical properties of low-doped BDD containing sp2 might be due partially to the high level of surface oxygen, the large work function, the low carrier density, and the existence of different types of sp2 carbon.

Original languageEnglish
Pages (from-to)2310-2316
Number of pages7
JournalJournal of the American Chemical Society
Issue number5
Publication statusPublished - 2020 Feb 5

ASJC Scopus subject areas

  • Catalysis
  • General Chemistry
  • Biochemistry
  • Colloid and Surface Chemistry


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