Wavepacket dynamics of hydrogen cyanide excited by intense ultrashort pulsed laser

Michihiko Sugawara; K. Yamamoto; Y. Fujimura

doi:10.1016/S0166-1280(09)80086-9

Wavepacket dynamics of hydrogen cyanide excited by intense ultrashort pulsed laser

Michihiko Sugawara, K. Yamamoto, Y. Fujimura

Research output: Contribution to journal › Article › peer-review

Abstract

Dynamics of hydrogen cyanide in the ground electronic state under an intense, impulsive excitation condition is theoretically studied based on the semiclassical theory of the molecule-radiation field interaction. Hydrogen migration in the HCN/HNC system, which originates from a simultaneous, IR-multiphoton absorption induced by such an impulsive excitation, is expressed in terms of the nuclear wavepacket propagation. Dynamic coupling between the CH stretching and HCN bending vibrational modes is shown to play an important role in the hydrogen migration process.

Original language	English
Pages (from-to)	77-82
Number of pages	6
Journal	Journal of Molecular Structure: THEOCHEM
Volume	310
DOIs	https://doi.org/10.1016/S0166-1280(09)80086-9
Publication status	Published - 1994
Externally published	Yes

ASJC Scopus subject areas

Biochemistry
Condensed Matter Physics
Physical and Theoretical Chemistry

Access to Document

10.1016/S0166-1280(09)80086-9

Cite this

@article{8aa7bcbbef0b468c802a6511902f84d5,

title = "Wavepacket dynamics of hydrogen cyanide excited by intense ultrashort pulsed laser",

abstract = "Dynamics of hydrogen cyanide in the ground electronic state under an intense, impulsive excitation condition is theoretically studied based on the semiclassical theory of the molecule-radiation field interaction. Hydrogen migration in the HCN/HNC system, which originates from a simultaneous, IR-multiphoton absorption induced by such an impulsive excitation, is expressed in terms of the nuclear wavepacket propagation. Dynamic coupling between the CH stretching and HCN bending vibrational modes is shown to play an important role in the hydrogen migration process.",

author = "Michihiko Sugawara and K. Yamamoto and Y. Fujimura",

year = "1994",

doi = "10.1016/S0166-1280(09)80086-9",

language = "English",

volume = "310",

pages = "77--82",

journal = "Journal of Molecular Structure: THEOCHEM",

issn = "0166-1280",

publisher = "Elsevier BV",

}

TY - JOUR

T1 - Wavepacket dynamics of hydrogen cyanide excited by intense ultrashort pulsed laser

AU - Sugawara, Michihiko

AU - Yamamoto, K.

AU - Fujimura, Y.

PY - 1994

Y1 - 1994

N2 - Dynamics of hydrogen cyanide in the ground electronic state under an intense, impulsive excitation condition is theoretically studied based on the semiclassical theory of the molecule-radiation field interaction. Hydrogen migration in the HCN/HNC system, which originates from a simultaneous, IR-multiphoton absorption induced by such an impulsive excitation, is expressed in terms of the nuclear wavepacket propagation. Dynamic coupling between the CH stretching and HCN bending vibrational modes is shown to play an important role in the hydrogen migration process.

AB - Dynamics of hydrogen cyanide in the ground electronic state under an intense, impulsive excitation condition is theoretically studied based on the semiclassical theory of the molecule-radiation field interaction. Hydrogen migration in the HCN/HNC system, which originates from a simultaneous, IR-multiphoton absorption induced by such an impulsive excitation, is expressed in terms of the nuclear wavepacket propagation. Dynamic coupling between the CH stretching and HCN bending vibrational modes is shown to play an important role in the hydrogen migration process.

UR - http://www.scopus.com/inward/record.url?scp=85025344247&partnerID=8YFLogxK

UR - http://www.scopus.com/inward/citedby.url?scp=85025344247&partnerID=8YFLogxK

U2 - 10.1016/S0166-1280(09)80086-9

DO - 10.1016/S0166-1280(09)80086-9

M3 - Article

AN - SCOPUS:85025344247

SN - 0166-1280

VL - 310

SP - 77

EP - 82

JO - Journal of Molecular Structure: THEOCHEM

JF - Journal of Molecular Structure: THEOCHEM

ER -

Wavepacket dynamics of hydrogen cyanide excited by intense ultrashort pulsed laser

Abstract

ASJC Scopus subject areas

Access to Document

Other files and links

Fingerprint

Cite this