@article{ff385dc47e5a43c2be9bc69e1c591ce4,
title = "1,2-cis-α-Stereoselective Glycosylation Utilizing a Glycosyl-Acceptor-Derived Borinic Ester and Its Application to the Total Synthesis of Natural Glycosphingolipids",
abstract = "1,2-cis-α-Stereoselective glycosylations were conducted using a 1,2-anhydroglucose donor and mono-ol acceptors in the presence of a glycosyl-acceptor-derived borinic ester. Reactions proceeded smoothly under mild conditions to provide the corresponding α-glycosides with high stereoselectivity in moderate to high yields. In addition, the present method was applied successfully to the direct glycosylation of a protected ceramide acceptor and the total synthesis of natural glycosphingolipids (GSLs).",
author = "Masamichi Tanaka and Daisuke Takahashi and Kazunobu Toshima",
note = "Funding Information: This research was supported in part by the MEXT-supported Program for the Strategic Research Foundation at Private Universities, 2012-2016, and JSPS KAKENHI Grant Numbers JP16H01161 in Middle Molecular Strategy and JP16K05781. Publisher Copyright: {\textcopyright} 2016 American Chemical Society.",
year = "2016",
month = oct,
day = "7",
doi = "10.1021/acs.orglett.6b02488",
language = "English",
volume = "18",
pages = "5030--5033",
journal = "Organic Letters",
issn = "1523-7060",
publisher = "American Chemical Society",
number = "19",
}