(+)-(1S,5R,6R)-6-[(S)-1-Hydroxy-2-(methoxymethyloxy)ethyl] -1-methyl-3-trichloromethyl-2-aza-4,7-dioxabicyclo[3.3.0]oct-2-en-8-one

Takeshi Oishi; Hiroki Oishi; Syun Tsuzaki; Takaaki Sato; Noritaka Chida

doi:10.1107/S1600536812042912

(+)-(1S,5R,6R)-6-[(S)-1-Hydroxy-2-(methoxymethyloxy)ethyl] -1-methyl-3-trichloromethyl-2-aza-4,7-dioxabicyclo[3.3.0]oct-2-en-8-one

Takeshi Oishi, Hiroki Oishi, Syun Tsuzaki, Takaaki Sato, Noritaka Chida

研究成果: Article › 査読

抄録

In the title compound, C₁₁H₁4Cl3NO₆, the fused five-membered oxazoline and tetrahydrofuran rings are essentially planar with maximum deviations of 0.069(1) and 0.031(1)Å, respectively, and make a dihedral angle of 64.23(11)°with each other. In the crystal, molecules are linked by O-H⋯O and C-H⋯O hydrogen bonds, forming chains along the b-axis direction. Further C-H⋯O hydrogen bonds are observed between the chains.

本文言語	English
ページ（範囲）	o3185
ジャーナル	Acta Crystallographica Section E: Structure Reports Online
巻	68
号	11
DOI	https://doi.org/10.1107/S1600536812042912
出版ステータス	Published - 2012 11月

ASJC Scopus subject areas

化学 (全般)
材料科学（全般）
凝縮系物理学

文献へのアクセス

10.1107/S1600536812042912

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フィンガープリント

「(+)-(1S,5R,6R)-6-[(S)-1-Hydroxy-2-(methoxymethyloxy)ethyl] -1-methyl-3-trichloromethyl-2-aza-4,7-dioxabicyclo[3.3.0]oct-2-en-8-one」の研究トピックを掘り下げます。これらがまとまってユニークなフィンガープリントを構成します。

引用スタイル

@article{210031fd37ac44409356d0163a095214,

title = "(+)-(1S,5R,6R)-6-[(S)-1-Hydroxy-2-(methoxymethyloxy)ethyl] -1-methyl-3-trichloromethyl-2-aza-4,7-dioxabicyclo[3.3.0]oct-2-en-8-one",

abstract = "In the title compound, C11H14Cl3NO6, the fused five-membered oxazoline and tetrahydrofuran rings are essentially planar with maximum deviations of 0.069(1) and 0.031(1){\AA}, respectively, and make a dihedral angle of 64.23(11)°with each other. In the crystal, molecules are linked by O-H⋯O and C-H⋯O hydrogen bonds, forming chains along the b-axis direction. Further C-H⋯O hydrogen bonds are observed between the chains.",

keywords = "R factor = 0.027, T = 90 K, data-to-parameter ratio = 12.2, mean{\= }(C-C) = 0.003 {\AA}, single-crystal X-ray study, wR factor = 0.069",

author = "Takeshi Oishi and Hiroki Oishi and Syun Tsuzaki and Takaaki Sato and Noritaka Chida",

year = "2012",

month = nov,

doi = "10.1107/S1600536812042912",

language = "English",

volume = "68",

pages = "o3185",

journal = "Acta Crystallographica Section E: Structure Reports Online",

issn = "1600-5368",

publisher = "International Union of Crystallography",

number = "11",

}

TY - JOUR

T1 - (+)-(1S,5R,6R)-6-[(S)-1-Hydroxy-2-(methoxymethyloxy)ethyl] -1-methyl-3-trichloromethyl-2-aza-4,7-dioxabicyclo[3.3.0]oct-2-en-8-one

AU - Oishi, Takeshi

AU - Oishi, Hiroki

AU - Tsuzaki, Syun

AU - Sato, Takaaki

AU - Chida, Noritaka

PY - 2012/11

Y1 - 2012/11

N2 - In the title compound, C11H14Cl3NO6, the fused five-membered oxazoline and tetrahydrofuran rings are essentially planar with maximum deviations of 0.069(1) and 0.031(1)Å, respectively, and make a dihedral angle of 64.23(11)°with each other. In the crystal, molecules are linked by O-H⋯O and C-H⋯O hydrogen bonds, forming chains along the b-axis direction. Further C-H⋯O hydrogen bonds are observed between the chains.

AB - In the title compound, C11H14Cl3NO6, the fused five-membered oxazoline and tetrahydrofuran rings are essentially planar with maximum deviations of 0.069(1) and 0.031(1)Å, respectively, and make a dihedral angle of 64.23(11)°with each other. In the crystal, molecules are linked by O-H⋯O and C-H⋯O hydrogen bonds, forming chains along the b-axis direction. Further C-H⋯O hydrogen bonds are observed between the chains.

KW - R factor = 0.027

KW - T = 90 K

KW - data-to-parameter ratio = 12.2

KW - mean ̄(C-C) = 0.003 Å

KW - single-crystal X-ray study

KW - wR factor = 0.069

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U2 - 10.1107/S1600536812042912

DO - 10.1107/S1600536812042912

M3 - Article

C2 - 23284496

AN - SCOPUS:84870948803

SN - 1600-5368

VL - 68

SP - o3185

JO - Acta Crystallographica Section E: Structure Reports Online

JF - Acta Crystallographica Section E: Structure Reports Online

IS - 11

ER -