A neutral Fe(iii) compound exhibiting a two-step spin transition and dielectric anomalies

Zhao Yang Li; Jing Wei Dai; Kevin J. Gagnon; Hong Ling Cai; Takashi Yamamoto; Yasuaki Einaga; Han Hua Zhao; Shinji Kanegawa; Osamu Sato; Kim R. Dunbar; Ren Gen Xiong

doi:10.1039/c3dt51554k

A neutral Fe(iii) compound exhibiting a two-step spin transition and dielectric anomalies

Zhao Yang Li, Jing Wei Dai, Kevin J. Gagnon, Hong Ling Cai, Takashi Yamamoto, Yasuaki Einaga, Han Hua Zhao, Shinji Kanegawa, Osamu Sato, Kim R. Dunbar, Ren Gen Xiong

化学科

研究成果: Article › 査読

27 被引用数 (Scopus)

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The mononuclear ferric compound Fe(H-5-Cl-thsa-Me)(5-Cl-thsa-Me) ·H₂O (1) was synthesized and characterized using powder/single-crystal X-ray diffraction, Mössbauer spectroscopy, differential scanning calorimetry (DSC), and magnetic susceptibility measurements. This photo-responsive compound shows reversible, two-step spin-crossover behaviour. Moreover, dielectric anomalies were observed during the spin transitions, demonstrating the multifunctional properties of compound 1.

本文言語	English
ページ（範囲）	14685-14688
ページ数	4
ジャーナル	Dalton Transactions
巻	42
号	41
DOI	https://doi.org/10.1039/c3dt51554k
出版ステータス	Published - 2013 11月 7

ASJC Scopus subject areas

無機化学

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title = "A neutral Fe(iii) compound exhibiting a two-step spin transition and dielectric anomalies",

abstract = "The mononuclear ferric compound Fe(H-5-Cl-thsa-Me)(5-Cl-thsa-Me) ·H2O (1) was synthesized and characterized using powder/single-crystal X-ray diffraction, M{\"o}ssbauer spectroscopy, differential scanning calorimetry (DSC), and magnetic susceptibility measurements. This photo-responsive compound shows reversible, two-step spin-crossover behaviour. Moreover, dielectric anomalies were observed during the spin transitions, demonstrating the multifunctional properties of compound 1.",

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doi = "10.1039/c3dt51554k",

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AU - Li, Zhao Yang

AU - Dai, Jing Wei

AU - Gagnon, Kevin J.

AU - Cai, Hong Ling

AU - Yamamoto, Takashi

AU - Einaga, Yasuaki

AU - Zhao, Han Hua

AU - Kanegawa, Shinji

AU - Sato, Osamu

AU - Dunbar, Kim R.

AU - Xiong, Ren Gen

PY - 2013/11/7

Y1 - 2013/11/7

N2 - The mononuclear ferric compound Fe(H-5-Cl-thsa-Me)(5-Cl-thsa-Me) ·H2O (1) was synthesized and characterized using powder/single-crystal X-ray diffraction, Mössbauer spectroscopy, differential scanning calorimetry (DSC), and magnetic susceptibility measurements. This photo-responsive compound shows reversible, two-step spin-crossover behaviour. Moreover, dielectric anomalies were observed during the spin transitions, demonstrating the multifunctional properties of compound 1.

AB - The mononuclear ferric compound Fe(H-5-Cl-thsa-Me)(5-Cl-thsa-Me) ·H2O (1) was synthesized and characterized using powder/single-crystal X-ray diffraction, Mössbauer spectroscopy, differential scanning calorimetry (DSC), and magnetic susceptibility measurements. This photo-responsive compound shows reversible, two-step spin-crossover behaviour. Moreover, dielectric anomalies were observed during the spin transitions, demonstrating the multifunctional properties of compound 1.

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SN - 1477-9226

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A neutral Fe(iii) compound exhibiting a two-step spin transition and dielectric anomalies

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