A novel LIESST iron(II) complex exhibiting a high relaxation temperature

S. Hayami; Z. Z. Gu; Y. Einaga; Y. Kobayasi; Y. Ishikawa; Y. Yamada; A. Fujishima; O. Sato

doi:10.1021/ic000708e

A novel LIESST iron(II) complex exhibiting a high relaxation temperature

S. Hayami, Z. Z. Gu, Y. Einaga, Y. Kobayasi, Y. Ishikawa, Y. Yamada, A. Fujishima, O. Sato

研究成果: Article › 査読

117 被引用数 (Scopus)

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The spin-crossover iron(II) complex [Fe(L)(CN)₂·H₂O (1) has been investigated. Complex 1 has a pentagonal bipyramidal structure which is seven-coordinated, containing an N₃O₂ macrocycle and two CN^- ligands. Water molecules bind the complex by means of hydrogen bonding. It was found that the complex 1 exhibited a light-induced excited spin state trapping (LIESST) effect. The relaxation temperature is above 130 K, which is the highest temperature for LIESST compounds reported so far.

本文言語	English
ページ（範囲）	3240-3242
ページ数	3
ジャーナル	Inorganic Chemistry
巻	40
号	13
DOI	https://doi.org/10.1021/ic000708e
出版ステータス	Published - 2001 6月 18
外部発表	はい

ASJC Scopus subject areas

物理化学および理論化学
無機化学

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10.1021/ic000708e

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title = "A novel LIESST iron(II) complex exhibiting a high relaxation temperature",

abstract = "The spin-crossover iron(II) complex [Fe(L)(CN)2·H2O (1) has been investigated. Complex 1 has a pentagonal bipyramidal structure which is seven-coordinated, containing an N3O2 macrocycle and two CN- ligands. Water molecules bind the complex by means of hydrogen bonding. It was found that the complex 1 exhibited a light-induced excited spin state trapping (LIESST) effect. The relaxation temperature is above 130 K, which is the highest temperature for LIESST compounds reported so far.",

author = "S. Hayami and Gu, {Z. Z.} and Y. Einaga and Y. Kobayasi and Y. Ishikawa and Y. Yamada and A. Fujishima and O. Sato",

year = "2001",

month = jun,

day = "18",

doi = "10.1021/ic000708e",

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T1 - A novel LIESST iron(II) complex exhibiting a high relaxation temperature

AU - Hayami, S.

AU - Gu, Z. Z.

AU - Einaga, Y.

AU - Kobayasi, Y.

AU - Ishikawa, Y.

AU - Yamada, Y.

AU - Fujishima, A.

AU - Sato, O.

PY - 2001/6/18

Y1 - 2001/6/18

N2 - The spin-crossover iron(II) complex [Fe(L)(CN)2·H2O (1) has been investigated. Complex 1 has a pentagonal bipyramidal structure which is seven-coordinated, containing an N3O2 macrocycle and two CN- ligands. Water molecules bind the complex by means of hydrogen bonding. It was found that the complex 1 exhibited a light-induced excited spin state trapping (LIESST) effect. The relaxation temperature is above 130 K, which is the highest temperature for LIESST compounds reported so far.

AB - The spin-crossover iron(II) complex [Fe(L)(CN)2·H2O (1) has been investigated. Complex 1 has a pentagonal bipyramidal structure which is seven-coordinated, containing an N3O2 macrocycle and two CN- ligands. Water molecules bind the complex by means of hydrogen bonding. It was found that the complex 1 exhibited a light-induced excited spin state trapping (LIESST) effect. The relaxation temperature is above 130 K, which is the highest temperature for LIESST compounds reported so far.

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VL - 40

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JO - Inorganic Chemistry

JF - Inorganic Chemistry

IS - 13

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A novel LIESST iron(II) complex exhibiting a high relaxation temperature

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