Allyl C-glycosidations of totally unprotected glycals and allyltrimethylsilane with trimethylsilyl trifluoromethanesulfonate (TMSOTf)

Kazunobu Toshima; Toru Ishizuka; Goh Matsuo; Masaya Nakata

doi:10.1016/S0040-4039(00)77276-5

Allyl C-glycosidations of totally unprotected glycals and allyltrimethylsilane with trimethylsilyl trifluoromethanesulfonate (TMSOTf)

Kazunobu Toshima, Toru Ishizuka, Goh Matsuo, Masaya Nakata

応用化学科

研究成果: Article › 査読

30 被引用数 (Scopus)

抄録

Allyl C-glycosidations of the totally unprotected glycals, L-rhamnal (1), D-glucal (2), D-galactal (3) and D-fucal (4), with allyltrimethylsilane (5) using TMSOTf proceeded much more effectively than those of the corresponding acetylated glycals 10∼13 to furnish the unprotected and 2,3-unsaturated allyl α-C-glycosides 6∼9 in high yields, respectively.

本文言語	English
ページ（範囲）	5673-5676
ページ数	4
ジャーナル	Tetrahedron Letters
巻	35
号	31
DOI	https://doi.org/10.1016/S0040-4039(00)77276-5
出版ステータス	Published - 1994 8月 1

ASJC Scopus subject areas

生化学
創薬
有機化学

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10.1016/S0040-4039(00)77276-5

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引用スタイル

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AU - Matsuo, Goh

AU - Nakata, Masaya

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