Ambient pressure phase transitions over Ir(1 1 1): At the onset of CO oxidation

N. Johansson, M. Andersen, Y. Monya, J. N. Andersen, H. Kondoh, J. Schnadt, J. Knudsen

研究成果: Article査読

12 被引用数 (Scopus)


In this study we report on the adsorbate structures on an Ir(1 1 1) surface during the phase transition from the inactive to the active state during CO oxidation. The CO oxidation over Pt(1 1 1) is used as a reference case. Where Pt(1 1 1) either is inactive and CO covered or active and O covered, Ir(1 1 1) exhibits a transition state with co-existing chemisorbed O and CO. The observed structural differences are explained in terms of DFT-calculated adsorption energies. For Pt(1 1 1) the repulsive CO-O interaction makes co-existing chemisorbed CO and O unfavourable, while for Ir(1 1 1) the stronger O and CO adsorption allows for overcoming the repulsive interaction. At the onset of CO oxidation over Ir(1 1 1), a CO structure containing defects forms, which enables O2 to dissociatively adsorb on the Ir(1 1 1) surface, thus enabling the CO oxidation reaction. At the mass transfer limit, the Ir(1 1 1) surface is covered by a chemisorbed O structure with defects; hence, the active surface is predominately chemisorbed O covered at a total pressure of 0.5 mbar and no oxide formation is observed.

ジャーナルJournal of Physics Condensed Matter
出版ステータスPublished - 2017 10月 12

ASJC Scopus subject areas

  • 材料科学(全般)
  • 凝縮系物理学


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