Asymmetric catalysis with bis(hydroxyphenyl)diamides/rare-earth metal complexes

Naoya Kumagai, Masakatsu Shibasaki

研究成果: Review article査読

59 被引用数 (Scopus)

抄録

A series of asymmetric catalysts composed of conformationally flexible amide-based chiral ligands and rare-earth metals was developed for proton-transfer catalysis. These ligands derived from amino acids provide an intriguing chiral platform for the formation of asymmetric catalysts upon complexation with rare-earth metals. The scope of this arsenal of catalysts was further broadened by the development of heterobimetallic catalytic systems. The cooperative function of hydrogen bonding and metal coordination resulted in intriguing substrate specificity and stereocontrol, and the dynamic nature of the catalysts led to a switch of their function. Herein, we summarize our recent exploration of this class of catalysts.

本文言語English
ページ(範囲)223-234
ページ数12
ジャーナルAngewandte Chemie - International Edition
52
1
DOI
出版ステータスPublished - 2013 1月 2
外部発表はい

ASJC Scopus subject areas

  • 触媒
  • 化学一般

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