C-arylglycosylation of unprotected free sugar

Kazunobu Toshima; Goh Matsuo; Toru Ishizuka; Masaya Nakata; Mitsuhiro Kinoshita

doi:10.1039/C39920001641

C-arylglycosylation of unprotected free sugar

Kazunobu Toshima
, Goh Matsuo
, Toru Ishizuka
, Masaya Nakata
, Mitsuhiro Kinoshita

応用化学科

研究成果: Article › 査読

34 被引用数 (Scopus)

抄録

Highly regio- and stereo-selective C-arylglycosylations of the protected free sugars 1-4, the unprotected methyl glycosides 6-9 and the unprotected free sugars 10 and 11 with 2-naphthol 5 are effectively realized by the combined use of TMSOTf-AgClO₄ (TMSOTf = trimethylsilyloxytrifluoromethanesulfonate) as a catalytic activator.

本文言語	English
ページ（範囲）	1641-1642
ページ数	2
ジャーナル	Journal of the Chemical Society D: Chemical Communications
号	22
DOI	https://doi.org/10.1039/C39920001641
出版ステータス	Published - 1992

ASJC Scopus subject areas

分子医療

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10.1039/C39920001641

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引用スタイル

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title = "C-arylglycosylation of unprotected free sugar",

abstract = "Highly regio- and stereo-selective C-arylglycosylations of the protected free sugars 1-4, the unprotected methyl glycosides 6-9 and the unprotected free sugars 10 and 11 with 2-naphthol 5 are effectively realized by the combined use of TMSOTf-AgClO4 (TMSOTf = trimethylsilyloxytrifluoromethanesulfonate) as a catalytic activator.",

author = "Kazunobu Toshima and Goh Matsuo and Toru Ishizuka and Masaya Nakata and Mitsuhiro Kinoshita",

year = "1992",

doi = "10.1039/C39920001641",

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journal = "Journal of the Chemical Society D: Chemical Communications",

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T1 - C-arylglycosylation of unprotected free sugar

AU - Toshima, Kazunobu

AU - Matsuo, Goh

AU - Ishizuka, Toru

AU - Nakata, Masaya

AU - Kinoshita, Mitsuhiro

PY - 1992

Y1 - 1992

N2 - Highly regio- and stereo-selective C-arylglycosylations of the protected free sugars 1-4, the unprotected methyl glycosides 6-9 and the unprotected free sugars 10 and 11 with 2-naphthol 5 are effectively realized by the combined use of TMSOTf-AgClO4 (TMSOTf = trimethylsilyloxytrifluoromethanesulfonate) as a catalytic activator.

AB - Highly regio- and stereo-selective C-arylglycosylations of the protected free sugars 1-4, the unprotected methyl glycosides 6-9 and the unprotected free sugars 10 and 11 with 2-naphthol 5 are effectively realized by the combined use of TMSOTf-AgClO4 (TMSOTf = trimethylsilyloxytrifluoromethanesulfonate) as a catalytic activator.

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M3 - Article

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C-arylglycosylation of unprotected free sugar

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